Topics in Catalysis

, Volume 53, Issue 15, pp 1231–1234

High Yield Conversion of Residual Pentoses into Furfural via Zeolite Catalysis and Catalytic Hydrogenation of Furfural to 2-Methylfuran

  • Jean Lessard
  • Jean-François Morin
  • Jean-François Wehrung
  • Delphine Magnin
  • Esteban Chornet
Original Paper

DOI: 10.1007/s11244-010-9568-7

Cite this article as:
Lessard, J., Morin, J., Wehrung, J. et al. Top Catal (2010) 53: 1231. doi:10.1007/s11244-010-9568-7

Abstract

Xylose was dehydrated over (H+) mordenite, using a continuous two-liquid-phase (aqueous-toluene) plug-flow reactor at 260 °C and 55 atm, with 98% conversion rate, 98% furfural molar yield, and 98% furfural selectivity (results from the first pass). Furfural in toluene was hydrogenated over a Cu/Fe catalyst, at 252 °C (gas-phase), in a 99% conversion rate to give 2-methylfuran in a 98% yield (same activity maintained for a 20-h operation).

Keywords

Xylose dehydrationFurfural hydrogenation2-MethylfuranAcid zeolite catalystHeterogeneous catalytic hydrogenation

Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Jean Lessard
    • 1
  • Jean-François Morin
    • 2
  • Jean-François Wehrung
    • 1
  • Delphine Magnin
    • 2
  • Esteban Chornet
    • 2
  1. 1.Département de ChimieUniversité de SherbrookeSherbrookeCanada
  2. 2.Département de Génie ChimiqueUniversité de SherbrookeSherbrookeCanada