Abstract
The respective coordination reactions of trans-[ReOCl3(PPh3)2] with N-[(4-oxo-4H-chromen-3-yl)methylidene]thiophene-2-carbohydrazide (Hchrtc) and N-[1,3-benzothiazol-2-ylmethylidene]thiophene-2-carbohydrazide (Hbztc) afforded two novel oxorhenium(V) complexes, cis-[ReOCl2(chrtc)(PPh3)] (1) and cis-[ReOCl2(bztc)(PPh3)] (2). These metal compounds were elucidated spectroscopically and their solid-state structures determined by single-crystal X-ray diffraction. The redox properties of the metal complexes were probed using cyclic and square wave voltammetry. The DNA interaction capabilities of 1 and 2 were gauged via UV/Vis spectroscopy DNA titrations and gel electrophoresis studies. A correlation is identified between the DNA cleavage observations and the redox potentials of the metal complexes.
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We are grateful to the University of KwaZulu-Natal, the National Research Foundation of South Africa (Grant No. TTK14042966698) and the Deutscher Akademischer Austauschdienst (DAAD) for financial support.
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Ismail, M.B., Booysen, I.N. & Akerman, M.P. Oxorhenium(V) complexes with bidentate carbohydrazide Schiff bases: synthesis, characterization and DNA interaction studies. Transit Met Chem 42, 405–412 (2017). https://doi.org/10.1007/s11243-017-0143-y
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DOI: https://doi.org/10.1007/s11243-017-0143-y