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Synthesis and characterization of a magnetically recoverable molybdenum(VI) nanocatalyst for eco-friendly oxidation of alcohols

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Abstract

A catalyst based on immobilization of a molybdenum(VI) Schiff base complex on γ-Fe2O3 magnetic nanoparticles has been synthesized and characterized. This catalyst was employed for the selective oxidation of alcohols to the corresponding carbonyl compounds in EtOH/H2O2. The catalyst can be easily separated from the reaction mixture by decantation using an external magnet and reused efficiently in five subsequent reaction cycles without any significant decrease in activity or selectivity.

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Acknowledgments

The support of this work by Vali-e-Asr University of Rafsanjan is acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Vali-e-Asr University of Rafsanjan, Rafsanjan, 77188-97111, Iran

    S. Saeednia, M. Hatefi Ardakani & M. Tavakoli Hafshejani

  2. Department of Nuclear Medicine and Molecular Imaging, Razavi Hospital, Mashhad, 9198613676, Iran

    Z. Pakdin Parizi

Authors
  1. S. Saeednia
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  2. M. Hatefi Ardakani
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  3. Z. Pakdin Parizi
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  4. M. Tavakoli Hafshejani
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Correspondence to S. Saeednia.

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Saeednia, S., Ardakani, M.H., Parizi, Z.P. et al. Synthesis and characterization of a magnetically recoverable molybdenum(VI) nanocatalyst for eco-friendly oxidation of alcohols. Transit Met Chem 41, 767–774 (2016). https://doi.org/10.1007/s11243-016-0077-9

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  • DOI: https://doi.org/10.1007/s11243-016-0077-9

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