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Surprises from an old reaction: a new 1-D heterometallic tris(pyridine-2-aldoximato)nickel(II)–sodium complex

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Abstract

The reaction of [Ni(pao)2Cl2] (pao = pyridine-2-aldoxime) with pyridine (py) in the presence of NaOH produced a 1-D polymeric heterometallic species, {[Ni2Na3(pao)6(OH) (H2O)](C5H5N)(H2O)2}n (1), along with a known bis(pyridine) complex, [Ni(pao)2(py)2] (2). Complex 1 represents a hitherto unknown example of a 1-D polymeric heterometallic structure composed of tris(pyridine-2-aldoximato)nickel(II) metalloligands. Further, an expeditious route to prepare the useful building block, [Ni(pao)2(py)2] (2), in good yield is reported.

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Acknowledgments

This work was supported by the CSIR, New Delhi, under Grant No. 01(2789)/14/EMR-II. We thank both the reviewers for their insightful comments on the paper, which helped us to considerably improve the quality of the manuscript.

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Authors and Affiliations

  1. Department of Chemical Sciences, Tezpur University, Napaam, Sonitpur, Assam, 784028, India

    Mamon Dey, Anuran Goswami & Nayanmoni Gogoi

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  1. Mamon Dey
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  2. Anuran Goswami
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  3. Nayanmoni Gogoi
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Correspondence to Nayanmoni Gogoi.

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Dey, M., Goswami, A. & Gogoi, N. Surprises from an old reaction: a new 1-D heterometallic tris(pyridine-2-aldoximato)nickel(II)–sodium complex. Transit Met Chem 41, 509–516 (2016). https://doi.org/10.1007/s11243-016-0046-3

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