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Coordination architectures of copper(II) coordination polymers constructed from bifunctional 5-substituted-tetrazole-carboxylate ligands

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Abstract

Three complexes of the bifunctional 5-substituted-tetrazolate-carboxylate ligands 3-(5-amino-2H-tetrazol-1(5H)-yl) propanoic acid (Hatzp), 5-(2-pyrimidyl)tetrazole-1-acetic acid (Hpymtza) and 1H-tetrazolate-5-acetic acid (Htza), namely mononuclear [Cu(atzp)2(H2O)4]·2H2O (1), a 1D polymeric chain structure [Cu(pymtza)2]·2H2O (2) and a 2D layer network [Cu(tza)2]·2DMF (3), were prepared and structurally characterized. The structures of these complexes are controlled by not only the different coordination modes of the tetrazole-carboxylate ligands but also the different 5-substituents of the tetrazole ring. Three different coordination modes of the tetrazolate-carboxylate ligands were observed: a tridentate N4-monodentate mode in complex 1, a tridentate N,N-chelated-O-bridged mode in complex 2 and a N,O-chelated-N-bridged mode in complex 3. Extensive hydrogen bonds play an important role in the construction of the supramolecular networks. The complexes show ligand-centered luminescence at room temperature in the solid state.

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Acknowledgments

We greatly appreciate financial support from the Foundation of Suzhou Science and Technology of Jiangsu Province of China (SYN201015), Natural Science Fund of Jiangsu Province of P. R. China (Nos. 10KJB430001, 14KJB150001), the Natural Science Foundation of Jiangsu Province (Grant No. BK2012210), the Opening Fund of Jiangsu Key Laboratory of Advanced Functional Materials (Grant No. 12KFJJ010) and the start-up Grant from CSLG (No. KYZ2014064Z).

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Authors and Affiliations

  1. Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, 215500, Jiangsu, People’s Republic of China

    Jie Yang, Jing Wang, Bo Wei, Lei Shen, Yu-Ting Min, Hong-Jian Cheng, Yue Xu, Jing Huang, Chen-Chen Wang, Xi Zhang, Mu-Lan Wu, Qiao-Yun Li & Gao-Wen Yang

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  1. Jie Yang
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Correspondence to Qiao-Yun Li or Gao-Wen Yang.

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Yang, J., Wang, J., Wei, B. et al. Coordination architectures of copper(II) coordination polymers constructed from bifunctional 5-substituted-tetrazole-carboxylate ligands. Transition Met Chem 41, 35–43 (2016). https://doi.org/10.1007/s11243-015-9994-2

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  • DOI: https://doi.org/10.1007/s11243-015-9994-2

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