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Synthesis, structures, and properties of copper(II), manganese(II), cobalt(II) and nickel(II) coordination polymers based on 3,3′-bipyridine-5-carboxylic acid

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Abstract

Assembly of 3,3′-bipyridine-5-carboxylic acid (3-Hbpc) with different transition metal salts produces four coordination polymers, [Cu(3-bpc)2] n (1), [M(3-bpc)2(H2O)2] n (M = Mn, 2; Co, 3; Ni, 4). All the complexes have been hydrothermally synthesized and characterized via physicochemical and spectroscopic methods. Single-crystal X-ray diffraction indicates that compound [Cu(3-bpc)2] n (1) shows the 1D coordination motif, and compounds [M(3-bpc)2(H2O)2] n (M = Mn, 2; Co, 3; Ni, 4) are isostructural, with similar 2D layered coordination structures. In addition, hydrogen-bonding interactions are observed in compounds 2–4 to further extend the coordination motifs. These complexes with different 1D and 2D coordination motifs indicate the metal-directed assembly. In addition, the thermal stability of all the complexes has also been studied and discussed.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (No. 21101116) and Innovation Foundation of Tianjin Normal University (No. 52XC1402).

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Authors and Affiliations

  1. College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic–Organic Hybrid Functional Material Chemistry, Tianjin Normal University, Tianjin, 300387, People’s Republic of China

    Guang-Peng Jing, Jian-Hua Guo & Jing Chen

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  1. Guang-Peng Jing
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  2. Jian-Hua Guo
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  3. Jing Chen
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Correspondence to Jing Chen.

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Jing, GP., Guo, JH. & Chen, J. Synthesis, structures, and properties of copper(II), manganese(II), cobalt(II) and nickel(II) coordination polymers based on 3,3′-bipyridine-5-carboxylic acid. Transition Met Chem 40, 763–768 (2015). https://doi.org/10.1007/s11243-015-9972-8

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  • DOI: https://doi.org/10.1007/s11243-015-9972-8

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