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Iron(II) and iron(III) complexes of 3,5-dimethyl diphenyldithiophosphate: synthesis, characterization and single-crystal X-ray analysis

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Abstract

3,5-Dimethyl diphenyldithiophosphate complexes of Fe(II) and Fe(III), formulated as [{(3,5-(CH3)2C6H3O)2PS2}2Fe{NC5H4(C2H5)-4}2] (1) and [{(3,5-(CH3)2C6H3O)2PS2}3Fe] (2), have been synthesized and characterized by physicochemical, spectroscopic and single-crystal X-ray analysis. The crystal structure of complex 1 reveals mononuclear units with the Fe(II) center chelated in bidentate fashion by four S atoms of the two diphenyldithiophosphate ligands. The N atoms from two donor ligands are axially coordinated, leading to octahedral geometry around Fe(II). In complex 2, the coordination around the Fe(III) atom is best described as distorted octahedral, formed by six S atoms from the three chelating diphenyldithiophosphate ligands. The main core of the system is comprised of four-membered (FeS2P)3 heteroatomic rings and Fe(III) centers.

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Scheme 1
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Fig. 2

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References

  1. Tripathi UN, Srivastava G, Mehrotra RC (1994) Transit Met Chem 19:564

    Article  CAS  Google Scholar 

  2. Hao Q, Yang X, Jian F, Lu L, Wang X, Razak IA, Chantrapromma S, Fun HK (2001) Acta Crystallogr C 57:42

    Article  CAS  Google Scholar 

  3. Zhang S, Li X, Wang J, Wen Y (2004) Indian J Chem 43A:1444

    CAS  Google Scholar 

  4. Drew MGB, Hopkins WA, Mitchell PCH, Colclough T (1986) J Chem Soc Dalton Trans 2:351

    Article  Google Scholar 

  5. Khajuria R, Kumar S, Kour G, Anthal S, Gupta VK, Kant R, Pandey SK (2014) J Coord Chem 67:2925

    Article  CAS  Google Scholar 

  6. Vogel AI (1978) A textbook of quantitative inorganic analysis, 4th edn. Longman, London

    Google Scholar 

  7. Sheldrick GM (2008) Acta Crystallogr A 64:112

    Article  CAS  Google Scholar 

  8. Farrugia LJ (1999) J Appl Crystallogr 32:837

    Article  CAS  Google Scholar 

  9. Nardelli M (1995) J Appl Crystallogr 28:659

    Article  CAS  Google Scholar 

  10. Spek AL (2009) Acta Crystallogr D 65:148

    Article  CAS  Google Scholar 

  11. Brandenburg K (1998) DIAMOND, Version 2.1. Crystal Impact GbR, Bonn, Germany

  12. Kalgotra N, Gupta B, Kumar K, Pandey SK (2012) Phosphorus. Sulfur Silicon Relat Elem 187:364

    Article  CAS  Google Scholar 

  13. Richard RE, Raymond RM, Norman VD (1972) Inorg Chem 11:1128

    Article  Google Scholar 

  14. Ewald AH, Martin RL, Sinn E, White AH (1969) Inorg Chem 8:1837

    Article  CAS  Google Scholar 

  15. van Koningsbruggen PJ, Maeda Y, Oshio H (2004) Top Curr Chem 233:259

    Article  Google Scholar 

  16. Lawton SL, Kokotailo GT (1969) Inorg Chem 8:2410

    Article  CAS  Google Scholar 

Download references

Acknowledgments

One of the authors (Rajni Kant) acknowledges the DST for the single-crystal X-ray diffractometer as a National Facility under Project No. SR/S2/CMP-47/2003.

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Authors and Affiliations

  1. Department of Chemistry, University of Jammu, Jammu, 180006, India

    Sandeep Kumar, Ruchi Khajuria, Atiya Syed & Sushil K. Pandey

  2. X-ray Crystallographic Laboratory, Department of Physics and Electronics, University of Jammu, Jammu, 180006, India

    Vivek K. Gupta & Rajni Kant

Authors
  1. Sandeep Kumar
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  2. Ruchi Khajuria
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  3. Atiya Syed
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  4. Vivek K. Gupta
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  5. Rajni Kant
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  6. Sushil K. Pandey
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Corresponding author

Correspondence to Sushil K. Pandey.

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Appendix: Supplementary data

Appendix: Supplementary data

CCDC 1051261 and 1051262 contain the supplementary crystallographic data for complexes 1 and 2. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44) 1223-336-033; or e-mail:deposit@ccdc.cam.ac.uk.

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Kumar, S., Khajuria, R., Syed, A. et al. Iron(II) and iron(III) complexes of 3,5-dimethyl diphenyldithiophosphate: synthesis, characterization and single-crystal X-ray analysis. Transition Met Chem 40, 519–523 (2015). https://doi.org/10.1007/s11243-015-9944-z

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  • DOI: https://doi.org/10.1007/s11243-015-9944-z

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