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Phenyl-functionalized diiron diselenolato complexes with intra- or inter-molecular bridging bidentate phosphine ligands

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Abstract

Treatment of 2-phenyl-1,3-bis(selenocyanate)propane with Fe3(CO)12 yielded the expected diiron diselenolato complex [(μ-SeCH2)2CHC6H5]Fe2(CO)6 (1). Reaction of complex 1 with bis(diphenylphosphine)methane (dppm) in refluxing xylene gave an intra-molecular phosphine bridging complex [(μ-SeCH2)2CHC6H5]Fe2(CO)4(μ-dppm) (2), while reaction of complex 1 with 1,1′-bis(diphenylphosphino)ferrocene (dppf) in the presence of the decarbonylating agent Me3NO afforded an inter-molecular phosphine bridging tetrairon complex {[(μ-SeCH2)2CHC6H5]Fe2(CO)5}2(μ, κ 1, κ 1-dppf) (3). All three complexes were characterized by physical–chemical and spectroscopic methods and for complexes 2 and 3 by X-ray crystallography. Their electrochemical behaviors, especially in the presence of HBF4 for 2, were investigated by cyclic voltammetry.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, 453003, People’s Republic of China

    Chang-Gong Li, Mao-Jin Cui, Feng Xue, Yong Zhu, Yong-Fang Li, Jing-Yan Shang & Hong-Ying Niu

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  1. Chang-Gong Li
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  2. Mao-Jin Cui
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  3. Feng Xue
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  4. Yong Zhu
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  5. Yong-Fang Li
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  7. Hong-Ying Niu
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Correspondence to Chang-Gong Li.

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Li, CG., Cui, MJ., Xue, F. et al. Phenyl-functionalized diiron diselenolato complexes with intra- or inter-molecular bridging bidentate phosphine ligands. Transition Met Chem 40, 493–500 (2015). https://doi.org/10.1007/s11243-015-9940-3

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