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Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2′-bipyridine) complexes of iron(II) and nickel(II) as cations

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Abstract

Four new compounds composed of chiral complex cations and anions: Δ-[Fe(bpy)3] Λ-[Fe(bpy)3][V4O8((2R,3R)-tart)2]·12H2O (1), Δ-[Fe(bpy)3]2Λ-[Fe(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]·24H2O (2), Δ-[Ni(bpy)3]Λ-[Ni(bpy)3][V4O8((2R,3R)-tart)2]·12H2O (3) and Δ-[Ni(bpy)3]2Λ-[Ni(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]·24H2O (4) have been prepared. The compounds have been characterized by spectral methods, and their thermal decomposition was studied by simultaneous DTA, TG measurements. The final products after dynamic decomposition and additional heating were Fe2V4O13 for 1 and 2 and Ni(VO3)2 for 3 and 4. The crystal structures determined for 1, 2 and 4 have evidenced that 1 is “hemiracemic” and 2 and 4 are “fully racemic” compounds.

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Acknowledgments

This work was supported by the Ministry of Education, Science, Research and Sport of the Slovak Republic (Grant No. VEGA 1/0336/13).

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University, Mlynská dolina, 842 15, Bratislava, Slovak Republic

    Peter Antal, Peter Schwendt, Jozef Tatiersky & Milan Drábik

  2. Faculty of Education, J. Selye University, Bratislavská cesta 3322, 945 01, Komárno, Slovak Republic

    Róbert Gyepes

  3. J. Heyrovský Institute of Physical Chemistry of the AS CR, v.v.i., Dolejškova 3, 182 23, Prague 8, Czech Republic

    Róbert Gyepes

  4. Institute of Inorganic Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, 845 36, Bratislava 45, Slovak Republic

    Milan Drábik

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  1. Peter Antal
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  2. Peter Schwendt
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  3. Jozef Tatiersky
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  4. Róbert Gyepes
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  5. Milan Drábik
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Correspondence to Jozef Tatiersky.

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Antal, P., Schwendt, P., Tatiersky, J. et al. Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2′-bipyridine) complexes of iron(II) and nickel(II) as cations. Transition Met Chem 39, 893–900 (2014). https://doi.org/10.1007/s11243-014-9873-2

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  • DOI: https://doi.org/10.1007/s11243-014-9873-2

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