Skip to main content
SpringerLink
Log in

Assembly of 1D and 3D cobalt(II) coordination polymers based on isophthalic acid and flexible benzimidazolyl-based ligands

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Two new metal–organic coordination polymers {[Co(L1)(nip)]·H2O} n (1) and [Co(L2)(ip)] n (2) (H2ip = isophthalic acid, L1 = 1,3-bis(benzimidazol-1-ylmethyl)benzene, L2 = 1,4-bis(5-methylbenzimidazol-1-ylmethyl)benzene, H2nip = 5-nitroisophthalic acid) have been synthesized under hydrothermal conditions and characterized by physicochemical and spectroscopic methods as well as single-crystal X-ray diffraction analysis. The analysis reveals that complex 1 has a 1D double chain structure connected by L1 and nip2− ligands, which is further assembled into a 3D bbf (moganite network) supermolecular framework via two types of C–H···O hydrogen bond interactions. Complex 2 possesses a 3D MOF with a four-connected cds (CdSO4 network) topology. The fluorescence and catalytic properties of the complexes for the degradation of Congo red have been investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Zheng L, Ye D, Xiong L, Xu J, Tao K, Zou Z et al (2013) Anal Chim Acta 768:69–75

    Article  CAS  Google Scholar 

  2. Yaghi OM, O’Keeffe M, Ockwig NW, Chae HK, Eddaoudi M, Kim J (2003) Nature 423:705–714

    Article  CAS  Google Scholar 

  3. Cui GH, Li JR, Tian JL, Bu XH, Batten SR (2005) Cryst Growth Des 5:1775–1780

    Article  CAS  Google Scholar 

  4. Liu YY, Liu B, Yang J, Ma JF (2013) Polyhedron 56:96–101

    Article  CAS  Google Scholar 

  5. Ming CL, Li YH, Li GY, Cui GH (2014) Transit Met Chem 39:477–485

    Article  CAS  Google Scholar 

  6. Piromchom J, Wannarit N, Boonmak J, Pakawatchai C, Youngme S (2014) Inorg Chem Comm 40:59–61

    Article  CAS  Google Scholar 

  7. Liu LL, Huang JJ, Wang XL, Liu GC, Yang S, Lin HY (2013) Inorg Chim Acta 394:715–722

    Article  CAS  Google Scholar 

  8. Li DS, Wu YP, Zhao J, Zhang J, Lu JY (2014) Coord Chem Rev 261:1–27

    Article  CAS  Google Scholar 

  9. Xiao SL, Qin L, Ma PJ, Cui GH (2013) Z Anorg Allg Chem 639:1855–1860

    Article  CAS  Google Scholar 

  10. Jiang H, Liu YY, Ma JF, Zhang WL, Yang J (2008) Polyhedron 27:2595–2602

    Article  CAS  Google Scholar 

  11. Liu GC, Huang JJ, Zhang JW, Wang XL, Lin HY (2013) Transit Met Chem 38:359–365

    Article  CAS  Google Scholar 

  12. Allen FH (2002) Acta Cryst B58:380–388

    Article  CAS  Google Scholar 

  13. Wang J, Lin ZJ, Ou YC, Yang NL, Zhang YH, Tong ML (2008) Inorg Chem 47:190–199

    Article  CAS  Google Scholar 

  14. Wang XY, Wang ZM, Gao S (2008) Chem Commun 3:281–294

    Article  Google Scholar 

  15. Sun YQ, Xu YY, Gao DZ, Zhang GY, Liu YX, Wang J, Liao DZ (2012) Dalton Trans 41:5704–5714

    Article  CAS  Google Scholar 

  16. Du M, Zhang ZH, You YP, Zhao XJ (2008) CrystEngComm 10:306–321

    Article  CAS  Google Scholar 

  17. Lucas JS, Bell LD, Gandolfo CM, LaDuca RL (2011) Inorg Chem Commun 378:269–279

    CAS  Google Scholar 

  18. Qin L, Wang LN, Ma PJ, Cui GH (2014) J Mol Struct 1059:202–207

    Article  CAS  Google Scholar 

  19. Wang XL, Hou LL, Zhang JW, Liu GC, Lin HY (2013) Polyhedron 61:65–72

    Article  CAS  Google Scholar 

  20. Wang XX, Liu YG, Li YH, Cui GH (2014) Transit Met Chem 39:461–467

    Article  CAS  Google Scholar 

  21. Aakeroy CB, Desper J, Elisabeth E, Helfrich BA, Levin B, Urbina JF (2005) Z Kristallogr 220:325–332

    Article  Google Scholar 

  22. Sheldrick GM (1996) SADABS. University of Göttingen, Germany

    Google Scholar 

  23. Sheldrick GM (2008) Acta Cryst A 64:112–122

    Article  CAS  Google Scholar 

  24. Blatov VA (2012) Struct Chem 23:955–963

    Article  CAS  Google Scholar 

  25. O’Keeffe M. Reticular chemistry structure. Resource (http://rcsr.anu.edu.au/)

  26. O’Keeffe M, Peskov MA, Ramsden SJ, Yaghi OM (2008) Acc Chem Res 41:1782–1789

    Article  Google Scholar 

  27. Gu XJ, Xue DF (2006) Cryst Growth Des 6:2551–2557

    Article  CAS  Google Scholar 

  28. Deacon GB, Phillips RJ (1980) Coord Chem Rev 33:227–250

    Article  CAS  Google Scholar 

  29. Geranmayeh S, Abbasi A, Skripkin MY, Badiei A (2012) Polyhedron 45:204–212

    Article  CAS  Google Scholar 

  30. Wang YT, Xu Y, Fan YT, Hou HW (2009) J Solid State Chem 182:2707–2715

    Article  CAS  Google Scholar 

  31. Huang XY, Yue KF, Jin JC, Liu JQ, Wang CJ, Wang YY, Shi QZ (2010) Inorg Chem Comm 13:338–341

    Article  CAS  Google Scholar 

  32. Allendorf MD, Bauer CA, Bhakta RK, Houk RJT (2009) Chem Soc Rev 38:1330–1352

    Article  CAS  Google Scholar 

  33. Wang XL, Zhang JX, Liu GC, Lin HY, Chen YQ, Kang ZH (2011) Inorg Chim Acta 368:207–215

    Article  CAS  Google Scholar 

  34. Mane VS, Vijay Babu PV (2013) J Taiwan Inst Chem Eng 44:81–88

    Article  CAS  Google Scholar 

  35. Ramirez JH, Duarte FM, Martins FG, Costa CA, Madeira LM (2009) Chem Eng J 148:394–404

    Article  CAS  Google Scholar 

  36. Jiang DM, Mallat T, Meie DM, Urakawa A, Baiker M (2010) J Catal 270:26–33

    Article  CAS  Google Scholar 

  37. Geng JC, Qin L, He CH, Cui GH (2012) Transit Met Chem 37:579–585

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Chemical Engineering, Hebei United University, Tangshan, 063009, Hebei, People’s Republic of China

    Xiao Xiao Wang, Ying Na Zhao, Guang Yue Li & Guang Hua Cui

Authors
  1. Xiao Xiao Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ying Na Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Guang Yue Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Guang Hua Cui
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Guang Hua Cui.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 632 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, X.X., Zhao, Y.N., Li, G.Y. et al. Assembly of 1D and 3D cobalt(II) coordination polymers based on isophthalic acid and flexible benzimidazolyl-based ligands. Transition Met Chem 39, 875–882 (2014). https://doi.org/10.1007/s11243-014-9871-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-014-9871-4

Keywords

Search

Navigation