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Preparation and crystal structure of a triple parallel interpenetrated copper coordination polymer based on a flexible bis(imidazole) ligand

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Abstract

A Cu(II) coordination polymer, [Cu(L)(bdc)] n (L = 1,4-bis(imidazole)butane, bdc = 1,3-benzenedicarboxylate) has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The complex is a rare example of a threefold parallel interpenetrated coordination bonding network based on undulant [Cu4(μ 2-L)2(μ 2-bdc)2] parallelograms with 44-sql layer. The heterogeneous catalytic activity of the complex was tested for the degradation of Congo red azo dye in a Fenton-like process in which the degradation efficiency reached 94 % after 100 min. Kinetic analysis indicates that the degradation rate of the dye can be approximated by pseudo-first-order kinetics.

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Acknowledgments

The authors thank the financial support from the National Natural Science Foundation of China (Nos. 11247281), and Excellent Youth Fund of Hebei Province Department of Education (Y2012010).

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei United University, Tangshan, 063009, Hebei, People’s Republic of China

    Li Qin, Guang Yue Li, Shu Lin Xiao & Guang Hua Cui

  2. Qian’an College, Hebei United University, Tangshan, 063009, Hebei, People’s Republic of China

    Yu Gu

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  1. Li Qin
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  2. Yu Gu
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  3. Guang Yue Li
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  4. Shu Lin Xiao
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  5. Guang Hua Cui
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Correspondence to Guang Hua Cui.

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Qin, L., Gu, Y., Li, G.Y. et al. Preparation and crystal structure of a triple parallel interpenetrated copper coordination polymer based on a flexible bis(imidazole) ligand. Transition Met Chem 38, 407–412 (2013). https://doi.org/10.1007/s11243-013-9705-9

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  • DOI: https://doi.org/10.1007/s11243-013-9705-9

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