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Synthesis, characterization, and luminescent properties of a series of silver(I) complexes with organic carboxylic acid and 1,3-bis(4-pyridyl)propane ligands

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Abstract

The reaction of AgNO3 with combinations of 1,3-bis(4-pyridyl)propane (bpp), pyridine-3,5-dicarboxylic acid (H2pdc), oxybis(benzoic acid) (H2oba), and 4,4′-oxidiphthalic acid (H4odpt) in aqueous alcohol/ammonia at room temperature produces crystals of [Ag2(bpp)2](pdc)·8H2O, [Ag2(bpp)2(H2O)](oba)·5H2O, and [Ag2(bpp)2(H2O)2](odpt)·2H2O. All three complexes consist of 1D infinite silver-bpp cationic chains, interspersed with organic carboxylate anions that provide charge compensation in the crystal structures. The lattice water molecules are situated among the framework of the crystal structure and show rich hydrogen-bonding interactions, which serve to orientate the organic carboxylate anions in the crystal packing, while the presence of Ag···N and Ag···Ag contacts strengthens the frameworks. The luminescent properties of the complexes have been investigated.

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Acknowledgments

The study was financially supported by Funding Project for Academic Human Resources Development in Institutions of Higher Learning Under the Jurisdiction of Beijing Municipality (Grant No. PHR201008372 and PHR201106124) and Open Research Fund Program of Key Laboratory of Urban Stormwater System and Water Environment (Ministry of Education), Beijing University of Civil Engineering and Architecture (Grant No. YH201101003), and the Research Fund of Beijing University of Civil Engineering and Architecture (101200702).

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Correspondence to Chong-chen Wang.

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Wang, Cc., Li, HY., Guo, GL. et al. Synthesis, characterization, and luminescent properties of a series of silver(I) complexes with organic carboxylic acid and 1,3-bis(4-pyridyl)propane ligands. Transition Met Chem 38, 275–282 (2013). https://doi.org/10.1007/s11243-012-9688-y

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  • DOI: https://doi.org/10.1007/s11243-012-9688-y

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