It was shown that interaction of photoreduced octamolybdate amine complexes of nickel(II) and copper(II) with silver(I) nitrate in aqueous solutions leads to formation of nanocomposite materials containing metallic silver nanoparticles. The nature of the 3d metal was established to affect the average size and dispersion of the silver nanoparticles, which are significantly greater in the composite based on the nickel complex. The photoluminescent properties of the materials obtained have been studied.
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This work was done with the partial financial support of the National Academy of Sciences of Ukraine, as part of the special comprehensive program for basic research on “Fundamental problems in nanostructural systems, nanomaterials, and nanotechnologies.”
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 51, No. 1, pp. 56-59, January-February, 2015.
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Barna, A.V., Tsymbal, L.V. & Lampeka, Y.D. Nanocomposites of Metallic Silver with Octamolybdate Amine Complexes of Nickel(II) and Copper(II). Theor Exp Chem 51, 62–66 (2015). https://doi.org/10.1007/s11237-015-9398-6
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DOI: https://doi.org/10.1007/s11237-015-9398-6