Abstract
The Schiff base compound (E)-1-(4-(4-(diethylamino)-2-hydroxybenzylideneamino)phenyl)ethanone has been synthesized and characterized by IR, UV–Vis, and 1H and 13C NMR techniques. These properties of title compound were also investigated from calculative point of view. UV–Vis spectra of the title compound were recorded in different organic solvents to investigate the dependence of tautomerism on solvent types. Calculated results reveal that its enol form is more stable than its keto form. A detailed analysis of the nature of the hydrogen bonding, using topological parameters, evaluated at bond critical points.
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Authors are grateful to the Damghan University for financial support.
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Kanaani, A., Ajloo, D., Ghasemian, H. et al. Synthesis, molecular structure, spectroscopic investigations and computational studies of (E)-1-(4-(4-(diethylamino)-2-hydroxybenzylideneamino)phenyl)ethanone. Struct Chem 26, 1095–1113 (2015). https://doi.org/10.1007/s11224-015-0571-2
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DOI: https://doi.org/10.1007/s11224-015-0571-2