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Structural insight into repeated-rhomboid coordination polymers from 4,4′-dithiodipyridine and zinc nitrate

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Abstract

Reaction of Zn(NO3)2·6H2O with the bent bridging ligand 4,4′-dithiodipyridine (dtdp), showing axial chirality, in the presence of the chelating 1,10-phenanthroline (phen) ligand in ethanol yielded [{Zn(μ-dtdp)2(H2O)2}(NO3)2·2C2H5OH·2H2O] n (1). In 1, Zn2+ ions are linked by two dtdp ligands of opposite chirality into a one-dimensional coordination polymer of the repeated-rhomboid type; the phen co-ligand was not encountered in the crystal. Pseudo-symmetry of the lattice is discussed for 1. Reaction of Zn(NO3)2·6H2O and dtdp in an ethanol/water mixture in absence of phen led to the known repeated-rhomboid coordination polymer [{Zn(NO3)(μ-dtdp)2(H2O)}NO3·4H2O] n (2), the crystal structure of which was redetermined at 110 K. At low temperature, the nitrato-κO ligand in one axial position of Zn2+ was found to be non-disordered as distinct from the room temperature structure (Horikoshi and Mikuriya, Cryst Growth Des 5:223–230, 2005). The Zn2+ ions in 2 are joined by two dtdp ligands of the same chirality.

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Acknowledgments

RWS would like to thank Professor William S. Sheldrick for helpful discussions and Professor Christian W. Lehmann for generous support. Financial support from Bayer Material Science AG and the Deutsche Forschungsgemeinschaft (DFG) is acknowledged.

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Authors and Affiliations

  1. Lehrstuhl für Analytische Chemie, Ruhr-Universität Bochum, Universitätsstraße 150, 44780, Bochum, Germany

    Rüdiger W. Seidel

  2. Lehrstuhl für Anorganische Chemie, Technische Universität Dortmund, Otto-Hahn-Straße 6, 44227, Dortmund, Germany

    Christina Dietz

  3. Institut für Anorganische Chemie, Rheinisch-Westfälische Technische Hochschule Aachen, Landoltweg 1, 52074, Aachen, Germany

    Iris M. Oppel

Authors
  1. Rüdiger W. Seidel
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  2. Christina Dietz
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  3. Iris M. Oppel
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Correspondence to Iris M. Oppel.

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Seidel, R.W., Dietz, C. & Oppel, I.M. Structural insight into repeated-rhomboid coordination polymers from 4,4′-dithiodipyridine and zinc nitrate. Struct Chem 22, 1225–1232 (2011). https://doi.org/10.1007/s11224-011-9811-2

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  • DOI: https://doi.org/10.1007/s11224-011-9811-2

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