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Supramolecular catalytic systems based on anionic amphiphiles and polyethyleneimine for hydrolytic cleavage of phosphorus ester bonds

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Abstract

Self-organization in individual and binary systems based on polyethyleneimine (PEI) and amphiphilic sulfonatocalix[4]resorcinarene was studied by conductometry, tensiometry, dynamic light scattering, and 1H NMR spectroscopy. The critical concentrations of micelle formation and aggregate sizes were determined. The enhancement of the catalytic effect on the hydrolysis of O-ethyl O-p-nitrophenyl chloromethylphosphonate was shown in the following series of the systems: PEI-water < PEI—calixarene-water < PEI—calixarene—LaIII—water.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    L. Ya. Zakharova, F. G. Valeeva, A. R. Ibragimova, M. A. Voronin, L. A. Kudryavtseva, V. V. Syakaev, E. Kh. Kazakova, Yu. E. Morozova, N. A. Makarova & A. I. Konovalov

  2. Kazan State Technological University, 68 ul. K. Marksa, 420015, Kazan, Russian Federation

    M. A. Voronin

  3. Nizhny Novgorod State Medical Academy, 10/1 pl. Minina, 603600, Nizhny Novgorod, Russian Federation

    N. B. Mel’nikova & O. E. Zemnyakova

Authors
  1. L. Ya. Zakharova
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  2. F. G. Valeeva
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  3. A. R. Ibragimova
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  4. M. A. Voronin
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  5. L. A. Kudryavtseva
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  6. V. V. Syakaev
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  7. E. Kh. Kazakova
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  8. Yu. E. Morozova
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  9. N. A. Makarova
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  10. N. B. Mel’nikova
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  11. O. E. Zemnyakova
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  12. A. I. Konovalov
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Corresponding author

Correspondence to L. Ya. Zakharova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 366–373, February, 2008.

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Zakharova, L.Y., Valeeva, F.G., Ibragimova, A.R. et al. Supramolecular catalytic systems based on anionic amphiphiles and polyethyleneimine for hydrolytic cleavage of phosphorus ester bonds. Russ Chem Bull 57, 374–382 (2008). https://doi.org/10.1007/s11172-008-0057-0

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  • DOI: https://doi.org/10.1007/s11172-008-0057-0

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