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Adsorption and anticorrosion behavior of 1-((pyridin-2-ylamino)(pyridin-4-yl)methyl)pyrrolidine-2,5-dione on mild steel surface in hydrochloric acid solution

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Abstract

New Mannich base 1-((pyridin-2-ylamino)(pyridin-4-yl)methyl)pyrrolidine-2,5-dione (SAP) was synthesized, characterized, and investigated as a corrosion inhibitor on mild steel (MS) in 1.0 M HCl using weight loss, electrochemical experiments, and theoretical calculations. Impedance spectra validated the decrease in the double-layer capacitance (C dl) and increase in the charge-transfer resistance (R CT) of the corrosion process due to the addition of the inhibitor. Tafel polarization studies proved that the inhibitor has a mixed type inhibitive nature with predominant control of cathodic reaction. A maximum inhibition efficiency of 88.7% from weight loss measurements and above 94.5% from electrochemical analysis were observed in the presence of 200 ppm of SAP, and the adsorption of SAP on MS surface in 1.0 M HCl was found to follow Langmuir’s adsorption isotherm. The calculated values of thermodynamic parameters predict the adsorption of SAP molecules on the MS surface was physical adsorption. FTIR, SEM–EDX, and AFM were used to characterize the surface morphology of the mild steel samples in the presence and absence of inhibitor. Density functional theory based quantum chemical calculations also fortifies the experimental inferences revealing SAP as good inhibitor.

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Acknowledgements

The author M. Jeeva wishes to acknowledge MHRD, Government of India, for a research fellowship. We thank DST-FIST for characterization facilities, Department of Chemistry, National Institute of Technology, Tiruchirappalli, India. Authors are highly thankful to Department of Chemistry, Gandhigram Rural Institute, Dindigul, Tamilnadu, India for SEM−EDX analysis, and STIC, Cochin University, Kerala, India for Elemental analysis.

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  1. Department of Chemistry, National Institute of Technology, Tiruchirappalli, Tamil Nadu, 620015, India

    Mani Jeeva & G. Venkatesa Prabhu

  2. Department of Chemistry, St. Joseph’s College, Tiruchirapalli, Tamil Nadu, 620002, India

    Maria susai Boobalan

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  1. Mani Jeeva
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  2. Maria susai Boobalan
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Correspondence to G. Venkatesa Prabhu.

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Jeeva, M., Boobalan, M.s. & Prabhu, G.V. Adsorption and anticorrosion behavior of 1-((pyridin-2-ylamino)(pyridin-4-yl)methyl)pyrrolidine-2,5-dione on mild steel surface in hydrochloric acid solution. Res Chem Intermed 44, 425–454 (2018). https://doi.org/10.1007/s11164-017-3112-3

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