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Poly(vinylpyrrolidinium) perchlorate as a new and efficient catalyst for the promotion of the synthesis of polyhydroquinoline derivatives via Hantzsch condensation

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Abstract

A green approach for the promotion of the synthesis of Hantzsch products using poly(vinylpyrrolidinium) perchlorate {[PVPH]ClO4} as a new modified polymeric catalyst in the absence of solvent is reported. The title catalyst is easily prepared and characterized using a variety of techniques including infrared spectra, X-ray diffraction, thermal gravimetric analysis, scanning electron microscopy, pH analysis, and Hammett acidity function. Some of the advantages of this novel synthetic method are: easy preparation of the catalyst, short reaction times, high to excellent yields of the products, simple and easy work-up procedure, and reusability of the catalyst.

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Acknowledgments

We are thankful to the University of Guilan Research Councils for the partial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, College of Sciences, University of Guilan, 41335, Rasht, Iran

    Masoumeh Abedini, Farhad Shirini & Maryam Mousapour

Authors
  1. Masoumeh Abedini
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  2. Farhad Shirini
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  3. Maryam Mousapour
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Correspondence to Masoumeh Abedini or Farhad Shirini.

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Abedini, M., Shirini, F. & Mousapour, M. Poly(vinylpyrrolidinium) perchlorate as a new and efficient catalyst for the promotion of the synthesis of polyhydroquinoline derivatives via Hantzsch condensation. Res Chem Intermed 42, 2303–2315 (2016). https://doi.org/10.1007/s11164-015-2150-y

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