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Comprehensive monitoring of the performance of homogenous and heterogeneous UV/H2O2/S2O8 2−/Fe2+ processes in mineralization of Acid Red 73

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Abstract

Degradation of an azo dye, Acid Red 73 (AR73), was examined in detail using the UV/H2O2/S2O8 2−/Fe2+ process. UV–Vis absorbance, total organic carbon, H2O2 concentration, and pH of solution were monitored during the mineralization process. The results indicated that the mineralization efficiency was optimized from 78.8 to 95.6 % as a result of increasing the initial concentration of S2O8 2− from 0.923 to 3.70 mM. The capability of this process was compared with those of UV/H2O2, UV/H2O2/Fe2+, and UV/H2O2/S2O8 2− processes. The UV/H2O2/S2O8 2−/Fe2+ process was more effective than other processes in degradation of AR73. Moreover, Fe2+ was immobilized on the surface of zeolite (ZSM5), and its immobilization effect was examined. Mineralization efficiency in the Fe2+ catalyzed process was higher than that of the Fe2+–ZSM5 catalyzed process.

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Acknowledgments

The authors thank the Université de Haute-Alsace (France) and University of Tabriz (Iran) for their support.

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Authors and Affiliations

  1. Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, 51666-16471, Tabriz, Iran

    Alireza Khataee

  2. Laboratoire de Génie des procédés des effluents, Ecole Nationale Supérieure de Chimie de Mulhouse, Université de Haute-Alsace, 3, rue Alfred Werner, 68093, Mulhouse Cedex, France

    Hamid Aleboyeh & Azam Aleboyeh

  3. Faculty of Chemistry, Kharazmi University, 15719-14911, Tehran, Iran

    Mohsen Sheydaei

Authors
  1. Alireza Khataee
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  2. Hamid Aleboyeh
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  3. Mohsen Sheydaei
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  4. Azam Aleboyeh
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Correspondence to Alireza Khataee.

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Khataee, A., Aleboyeh, H., Sheydaei, M. et al. Comprehensive monitoring of the performance of homogenous and heterogeneous UV/H2O2/S2O8 2−/Fe2+ processes in mineralization of Acid Red 73. Res Chem Intermed 42, 571–580 (2016). https://doi.org/10.1007/s11164-015-2042-1

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  • DOI: https://doi.org/10.1007/s11164-015-2042-1

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