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A selective fluorescence probe for copper(II) ion in aqueous solution based on 4-(1,4,5-triphenyl-1H-imidazol-2-yl)anilinyl acetates

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Abstract

A novel fluorescent probe potassium 4-(1,4,5-triphenyl-1H-imidazol-2-yl)anilinyl acetate (PPIA) was designed and synthesized. It exhibited very strong sensitive, selective, and irreversible for Cu2+ over other commonly coexistent metal ions (Ca2+, Mg2+, Ni2+, Co2+, Cu+, Hg2+, Zn2+, Ba2+, Ag+, and Cd2+) in aqueous environment (pH 7.4). Moreover, according to the Job plot, 2:1 stoichiometry between PPIA and Cu2+ was deduced in aqueous media. A B3LYP/6-31 G(d) basis set was employed for optimization of PPIA and PPIA·Cu2+ complex.

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Acknowledgments

This work was supported by the Science Fund for Young Scholars of Heilongjiang Province of China (No. QC2009C61), the Program for Education Department of Heilongjiang Province (No. 12541862).

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Authors and Affiliations

  1. Chemistry and Chemical Engineering Institute, Qiqihar University, Qiqihar, 161006, China

    Bing Zhao, Yu Xu, Mingjie Ma, Wei Kan & Qigang Deng

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  1. Bing Zhao
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  2. Yu Xu
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  3. Mingjie Ma
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  4. Wei Kan
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  5. Qigang Deng
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Correspondence to Qigang Deng.

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Zhao, B., Xu, Y., Ma, M. et al. A selective fluorescence probe for copper(II) ion in aqueous solution based on 4-(1,4,5-triphenyl-1H-imidazol-2-yl)anilinyl acetates. Res Chem Intermed 41, 8031–8040 (2015). https://doi.org/10.1007/s11164-014-1875-3

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  • DOI: https://doi.org/10.1007/s11164-014-1875-3

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