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Improved hydrogen storage capacity by hydrogen spillover and fine structural characterization of MIL-100 metal organic frameworks

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Abstract

The MIL-100 metal organic framework was synthesized through solvothermal route, modified with Pt-loaded active carbon and H2 adsorption capacity was evaluated. The maximum specific surface area of MIL-100 was obtained upto 1,960 m2 g−1 with a type I adsorption isotherm confirmed from N2 adsorption isotherms. The pristine MIL-100 was modified with 5 wt% Pt-loaded activated carbon and the carbonyl bridge was established to facilitate the hydrogen spillover effect. The hydrogen storage capacity of modified MIL-100 was 0.41 wt% measured at 31 bar and 298 K. This value is much higher than that of pristine MIL-100. XANES spectra indicated that the valency of central chromium metal ions of MIL-100 structure was Cr(III). EXAFS data also revealed that MIL-100 had a first shell of Cr–O bonding with bond distance of 1.965 Å and the coordination number of 4.8.

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Acknowledgments

The financial support of the Ministry of Science and Technology (MOST), Taiwan (MOST 103-3113-E-008-001 and MOST 103-3113-E-008-003) is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemical Engineering and Materials Science/Environmental Technology Research Center, Yuan Ze University, Chung-Li, 320, Taiwan, Republic of China

    Abhijit Krishna Adhikari, Kuen-Song Lin & Chao-Shuen Chang

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  1. Abhijit Krishna Adhikari
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Correspondence to Kuen-Song Lin.

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Adhikari, A.K., Lin, KS. & Chang, CS. Improved hydrogen storage capacity by hydrogen spillover and fine structural characterization of MIL-100 metal organic frameworks. Res Chem Intermed 41, 7655–7667 (2015). https://doi.org/10.1007/s11164-014-1850-z

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