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Preparation and properties of β-cyclodextrins polymer used as calcium carbonate scale inhibitor containing fluorescent groups

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Abstract

In an attempt to control CaCO3 deposits in industrial recycling water systems, a maleic anhydride-β-cyclodextrins-acrylic acid-8-hydroxy-1, 3, 6-pyrenetrisulfonic acid trisodium salt (MA–β-CD–AA–PA) copolymer was synthesized by free-radical polymerization. The structure of the copolymer was characterized using FT-IR, 1H NMR, and TGA. The MA–β-CD–AA–PA exhibited an excellent ability to control inorganic minerals, with 95.8 % CaCO3 inhibition at level of 10 mg l−1 MA–β-CD–AA–PA, which suggested that the prepared copolymer was an excellent scale inhibitor. The copolymer showed the same fluorescence as pyranine. The fluorescence intensity of the copolymer was directly proportional to its concentration.

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Abbreviations

β-CD:

β-Cyclodextrins

HEDP:

1-Hydroxy ethylidene-1, 1-diphosphonic acid

TMPA:

1-Hydroxy ethylidine-1, thiomorpholin-4-ylmethyl-phosphonic acid

HMDTMP:

Hexa methylene diamine tetra methyl-phosphonic acid

MA:

Maleic anhydride

AA:

Acrylic acid

PFH:

Poly (9, 9-dihexyl-2, 7-fluorenediyl)

PA:

8-Hydroxy-1, 3, 6-pyrenetrisulfonic acid trisodium salt

TGA:

Thermogravimetric analysis

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Acknowledgments

The authors are thankful to Pro. Mina Luo for her great help in the mechanism studies.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, 610500, Sichuan, China

    Keying Wu, Fu Chen, Yangyang Liu & Jiao Luo

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  1. Keying Wu
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  2. Fu Chen
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  3. Yangyang Liu
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  4. Jiao Luo
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Correspondence to Fu Chen.

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Wu, K., Chen, F., Liu, Y. et al. Preparation and properties of β-cyclodextrins polymer used as calcium carbonate scale inhibitor containing fluorescent groups. Res Chem Intermed 41, 7617–7630 (2015). https://doi.org/10.1007/s11164-014-1847-7

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  • DOI: https://doi.org/10.1007/s11164-014-1847-7

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