Skip to main content
SpringerLink
Log in

Poly(4-vinylpyridine-hexadecyl bromide) as corrosion inhibitor for mild steel in acid chloride solution

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

The influence of the addition of poly(4-vinylpyridine-hexadecyl bromide) P4VP-Alkyl 50 % newly synthesized on the corrosion of mild steel in molar hydrochloric acid has been investigated by weight-loss measurements combined with linear potential scan voltammetry (I–E) and electrochemical impedance spectroscopy (EIS). The polymer reduces the corrosion rate and the inhibition efficiency (E %) of P4VP-Alkyl 50 % increases with its concentration and attains 95 % at 300 mg/L. E % obtained from cathodic Tafel plots, EIS, and gravimetric methods were in good agreement. The inhibitor was adsorbed on the iron surface according to the Langmuir adsorption isotherm model. Polarization measurements also show that the compound acts as a cathodic inhibitor.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Scheme 1
Scheme 2
Schema 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. H. Bhandari, V. Choudhary, S.K. Dhawan, Synth. Met. 161, 753 (2011)

    Article  CAS  Google Scholar 

  2. I. Elouali, B. Hammouti, A. Aouniti, Y. Ramli, M. Azougagh, E.M. Essassi, M. Bouachrine, J. Mater. Environ. Sci. 1, 1 (2010)

    CAS  Google Scholar 

  3. M.B. Nemer, Y.L. Xiong, A.E. Ismail, J.H. Jang, Chem. Geol. 280, 26 (2011)

    Article  CAS  Google Scholar 

  4. J. Soltis, D. Krouse, N. Laycock, Corros. Sci. 53, 2152 (2011)

    Article  CAS  Google Scholar 

  5. M.A. Salam, S.S. Al-Juaid, A.H. Qusti, A.A. Hermas, Synth. Met. 161, 153 (2011)

    Article  CAS  Google Scholar 

  6. L. Speckert, G.T. Burstein, Corros. Sci. 53, 534 (2011)

    Article  CAS  Google Scholar 

  7. T. Stephenson, A. Kubis, M. Derakhshesh, M. Hazelton, C. Holt, P. Eaton, B. Newman, A. Hoff, M. Gray, D. Mitlin, Energy Fuels 25, 4540 (2011)

    Article  CAS  Google Scholar 

  8. S.A. Umoren, Y. Li, F.H. Wang, Corros. Sci. 53, 1778 (2011)

    Article  CAS  Google Scholar 

  9. A. Chetouani, M. Daoudi, B. Hammouti, T. Ben Hadda, M. Benkaddour, Corros. Sci. 48, 2987 (2006)

    Article  CAS  Google Scholar 

  10. A. Chetouani, B. Hammouti, T. Benhadda, M. Daoudi, Appl. Surf. Sci. 249, 375 (2005)

    Article  CAS  Google Scholar 

  11. A. Chetouani, B. Hammouti, Bull. Electrochem. 20, 343 (2004)

    CAS  Google Scholar 

  12. C. Chetouani, K. Medjahed, K.E. Sid-Lakhdar, B. Hammouti, M. Benkaddour, A. Mansri, Corros. Sci. 46, 2421 (2004)

    Article  CAS  Google Scholar 

  13. A. Chetouani, A. Aouniti, B. Hammouti, N. Benchat, T. Benhadda, S. Kertit, Corros. Sci. 45, 1675 (2003)

    Article  CAS  Google Scholar 

  14. A. Chetouani, B. Hammouti, Bull. Electrochem. 19, 23 (2003)

    CAS  Google Scholar 

  15. A. Chetouani, K. Medjahed, K.E. Benabadji, B. Hammouti, S. Kertit, A. Mansri, Prog. Org. Coat. 46, 312 (2003)

    Article  CAS  Google Scholar 

  16. A. Chetouani, B. Hammouti, A. Aouniti, N. Benchat, T. Benhadda, Prog. Org. Coat. 45, 373 (2002)

    Article  CAS  Google Scholar 

  17. O.K. Abiola, M.O. John, P.O. Asekunowo, P.C. Okafor, O.O. James, Green Chem. Lett. Rev. 4, 273 (2011)

    Article  CAS  Google Scholar 

  18. D. Bankiewicz, E. Alonso-Herranz, P. Yrjas, T. Lauren, H. Spliethoff, M. Hupa, Energy Fuels 25, 3476 (2011)

    Article  CAS  Google Scholar 

  19. M. Behpour, S.M. Ghoreishi, N. Mohammadi, M. Salavati-Niasari, Corros. Sci. 53, 3380 (2011)

    Article  CAS  Google Scholar 

  20. K. Laarej, M. Bouachrine, S. Radi, S. Kertit, B. Hammouti, J. Chem. 7, 419 (2010)

    CAS  Google Scholar 

  21. K. Barouni, L. Bazzi, R. Salghi, M. Mihit, B. Hammouti, A. Albourine, S. El Issami, Mater. Lett. 62, 3325 (2008)

    Article  CAS  Google Scholar 

  22. M. Bouklah, A. Attayibat, S. Kertit, A. Ramdani, B. Hammouti, Appl. Surf. Sci. 242, 399 (2005)

    Article  CAS  Google Scholar 

  23. A. Ouchrif, M. Zegmout, B. Hammouti, A. Dafali, M. Benkaddour, A. Ramdani, S. Elkadiri, Prog. Org. Coat. 53, 292 (2005)

    Article  CAS  Google Scholar 

  24. M. Zerfaoui, B. Hammouti, H. Oudda, M. Benkaddour, S. Kertit, Bull. Electrochem. 20, 433 (2004)

    CAS  Google Scholar 

  25. M. Zerfaoui, H. Oudda, B. Hammouti, S. Kertit, M. Benkaddour, Prog. Org. Coat. 51, 134 (2004)

    Article  CAS  Google Scholar 

  26. M.A. Amin, K.F. Khaled, Q. Mohsen, H.A. Arida, Corros. Sci. 52, 1684 (2010)

    Article  CAS  Google Scholar 

  27. N. Bertrand, C. Desgranges, D. Poquillon, M.C. Lafont, D. Monceau, Oxid. Met. 73, 139 (2010)

    Article  CAS  Google Scholar 

  28. K. Kamaraj, V. Karpakam, S. Sathiyanarayanan, G. Venkatachari, Mater. Chem. Phys. 122, 123 (2010)

    Article  CAS  Google Scholar 

  29. G. Bereket, E. Hur, Prog. Org. Coat. 65, 116 (2009)

    Article  CAS  Google Scholar 

  30. Z.H. Guo, K. Shin, A.B. Karki, D.P. Young, R.B. Kaner, H.T. Hahn, J. Nanopart. Res. 11, 1441 (2009)

    Article  CAS  Google Scholar 

  31. N.A. Negm, M.F. Zaki, J. Dispers. Sci. Technol. 30, 649 (2009)

    Article  CAS  Google Scholar 

  32. R.M. Coleman, J. Fuoss, Am. Chem. Soc. 11, 5472 (1955)

    Article  Google Scholar 

  33. J. Morcellet, C. Loucheux, Makromol. Chem. 176, 315 (1975)

    Article  Google Scholar 

  34. S. Pradny, Sevcik. Makromol. Chem. 188, 2875 (1987)

    Article  CAS  Google Scholar 

  35. S. Dragan, I. Petrariu, M. Dima, J. Polym. Sci. Polym. Chem. Ed. 38, 2881 (1981)

    Article  Google Scholar 

  36. M. Prady, S. Sevcik, Makromol. Chem. 187, 2191 (1986)

    Article  Google Scholar 

  37. E. Choukchou-B, I. Benabadji, J. François, A. Mansri, Eur. Polym. J. 39, 297 (2003)

    Article  Google Scholar 

  38. A. Mansri, Y. Frère, C. Chevino, Ph. Gramain, Des. Monomers Polym. 3, 55 (2000)

    Article  CAS  Google Scholar 

  39. F.Z. Bouanis, C. Jama, M. Traisnel, F. Bentiss, Corros. Sci. 52, 3180 (2010)

    Article  CAS  Google Scholar 

  40. F. Bentiss, C. Jama, B. Mernari, H. El Attari, L. El Kadi, M. Lebrini, M. Traisnel, M. Lagrenee, Corros. Sci. 51, 1628 (2009)

    Article  CAS  Google Scholar 

  41. S. Kertit, B. Hammouti, Appl. Surf. Sci. 93, 59 (1996)

    Article  CAS  Google Scholar 

  42. F. Gesmundo, F. Viani, Mater. Chem. Phys. 20, 513 (1988)

    Article  CAS  Google Scholar 

  43. A. Doner, R. Solmaz, M. Ozcan, G. Kardas, Corros. Sci. 53, 2902 (2011)

    Article  Google Scholar 

  44. A. Doner, G. Kardas, Corros. Sci. 53, 4223 (2011)

    Article  CAS  Google Scholar 

  45. M. Dudukcu, Materials and Corrosion-Werkstoffe Und Korrosion 62, 264 (2011)

    Article  CAS  Google Scholar 

  46. B.D. Mert, M.E. Mert, G. Kardas, B. Yazici, Corros. Sci. 53, 4265 (2011)

    Article  CAS  Google Scholar 

  47. M. Lebrini, M. Traisnel, M. Lagrenee, B. Mernari, F. Bentiss, Corros. Sci. 50, 473 (2008)

    Article  CAS  Google Scholar 

  48. K. Tebbji, H. Oudda, B. Hammouti, M. Benkaddour, S.S. Al-Deyab, A. Aouniti, S. Radi, A. Ramdani, Res. Chem. Intermed. 37, 985 (2011)

    Article  CAS  Google Scholar 

  49. D.P. Schweinsberg, V. Ashworth, Corros. Sci. 28, 539 (1988)

    Article  CAS  Google Scholar 

  50. A.B. Tadros, B.A. Abdelnabey, J. Electroanal. Chem. 246, 433 (1988)

    Article  CAS  Google Scholar 

  51. F. Bentiss, M. Lagrenee, M. Traisnel, B. Mernari, H. Elattari, J. Appl. Electrochem. 29, 1073 (1999)

    Article  CAS  Google Scholar 

  52. V. Hluchan, B.L. Wheeler, N. Hackerman, Werkstoffe Und Korrosion-Mater. Corros 39, 512 (1988)

    Article  CAS  Google Scholar 

  53. K. Juttner, W.J. Lorenz, Werkstoffe Und Korrosion-Mater. Corr. 39, 561 (1988)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. LAEPO, Département de chimie, Faculté des sciences, Université de Tlemcen, B.P.119, 13000, Tlemcen, Algeria

    S. Belkaid & A. Mansri

  2. LCAE-URAC18, Faculté des Sciences, Université Mohammed Premier, Oujda, Morocco

    K. Tebbji, A. Chetouani & Belkheir Hammouti

  3. Laboratoire de chimie physique, Centre Pédagogique Régional, Oujda, Morocco

    A. Chetouani

Authors
  1. S. Belkaid
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Tebbji
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Mansri
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Chetouani
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Belkheir Hammouti
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Belkheir Hammouti.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Belkaid, S., Tebbji, K., Mansri, A. et al. Poly(4-vinylpyridine-hexadecyl bromide) as corrosion inhibitor for mild steel in acid chloride solution. Res Chem Intermed 38, 2309–2325 (2012). https://doi.org/10.1007/s11164-012-0547-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-012-0547-4

Keywords

Search

Navigation