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Potential solvents in coupling reactions catalyzed by Cu(II)Fe(III)-layered double hydroxide in a continuous-flow reactor

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Abstract

The stability of Cu(II)Fe(III)-layered double hydroxide [Cu(II)Fe(III)-LDH] was tested in many solvents (chloroform, acetonitrile, acetone, methanol, ethanol, dichloromethane, dimethyl sulfoxide, N,N-dimethyl-formamide, N-methyl-2-pyrrolidone, ethyl acetate, toluene, diethyl ether, tetrahydrofuran, 2-propanol, hexane) in a continuous-flow reactor under conditions applicable for a wide range of reactions (temperature: 25–120 °C, pressure: 50 bar, flow rate: 0.5 mL min−1). The structures of the as-prepared and the treated catalyst samples were studied by X-ray diffractometry. The LDH remained structurally unharmed in many solvents even at the highest temperature applied; however, completely free choice was possible only at 25 °C.

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Acknowledgements

This work was supported by the NKFIH Grants 106234 and K115731. SBÖ acknowledges the award of a János Bolyai Research Scholarship and a postdoctoral fellowship (Postdoctoral Research Program) from the Hungarian Academy of Sciences.

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Authors and Affiliations

  1. Department of Organic Chemistry, University of Szeged, Dóm tér 8, Szeged, 6720, Hungary

    Rebeka Mészáros & István Pálinkó

  2. Institute of Pharmaceutical Chemistry, University of Szeged, Eötvös u. 6, Szeged, 6720, Hungary

    Rebeka Mészáros, Sándor B. Ötvös & Ferenc Fülöp

  3. MTA-SZTE Stereochemistry Research Group, University of Szeged, Eötvös u. 6, Szeged, 6720, Hungary

    Sándor B. Ötvös & Ferenc Fülöp

  4. Department of Applied and Environmental Chemistry, University of Szeged, Rerrich Béla tér 1, Szeged, 6720, Hungary

    Zoltán Kónya & Ákos Kukovecz

  5. MTA-SZTE Reaction Kinetics and Surface Chemistry Research Group, Rerrich Béla tér 1, Szeged, 6720, Hungary

    Zoltán Kónya

  6. MTA-SZTE “Lendület” Porous Nanocomposites Research Group, Rerrich Béla tér 1, Szeged, 6720, Hungary

    Ákos Kukovecz

  7. Department of Inorganic and Analytical Chemistry, University of Szeged, Dóm tér 7, Szeged, 6720, Hungary

    Pál Sipos

Authors
  1. Rebeka Mészáros
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  2. Sándor B. Ötvös
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  3. Zoltán Kónya
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  4. Ákos Kukovecz
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  5. Pál Sipos
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  6. Ferenc Fülöp
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  7. István Pálinkó
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Correspondence to István Pálinkó.

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Mészáros, R., Ötvös, S.B., Kónya, Z. et al. Potential solvents in coupling reactions catalyzed by Cu(II)Fe(III)-layered double hydroxide in a continuous-flow reactor. Reac Kinet Mech Cat 121, 345–351 (2017). https://doi.org/10.1007/s11144-016-1133-3

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  • DOI: https://doi.org/10.1007/s11144-016-1133-3

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