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The epoxidation of diallyl ether to allyl-glycidyl ether over the TS-1 catalyst

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Abstract

Research on the epoxidation of diallyl ether (DAE) to allyl-glycidyl ether with 30 wt% hydrogen peroxide and in the presence of the TS-1 catalyst is presented. In this work, methanol was tested as the solvent. The influence of the following parameters was studied: the temperature 25–80 °C, the molar ratio of DAE/H2O2 0.25:1–5:1, the solvent concentration 10–90 wt%, the content of the TS-1 catalyst 1–9 wt% and the reaction time 15–240 min. Because the effective conversion of hydrogen peroxide was relatively low during the studies, after establishing the most beneficial conditions for the epoxidation of DAE, the influence of an addition of the chosen inorganic salt—KH2PO4 on the effective conversion of hydrogen peroxide and other functions characterized this process was also tested.

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Authors and Affiliations

  1. Institute of Organic Chemical Technology, West Pomeranian University of Technology Szczecin, Pułaskiego 10, 70-322, Szczecin, Poland

    A. Wróblewska, E. Drewnowska & A. Gawarecka

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  1. A. Wróblewska
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  2. E. Drewnowska
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  3. A. Gawarecka
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Correspondence to A. Wróblewska.

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Wróblewska, A., Drewnowska, E. & Gawarecka, A. The epoxidation of diallyl ether to allyl-glycidyl ether over the TS-1 catalyst. Reac Kinet Mech Cat 118, 719–731 (2016). https://doi.org/10.1007/s11144-016-1028-3

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  • DOI: https://doi.org/10.1007/s11144-016-1028-3

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