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A simple approach to the preparation of H6P2W18O62/Cu3(BTC)2 (BTC = 1,3,5-benzenetricarboxylate) and its catalytic performance in the synthesis of acetals/ketals

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Abstract

H6P2W18O62/Cu3(BTC)2 (BTC = 1,3,5-benzenetricarboxylate) as a new catalyst was prepared by the impregnation method and used to synthesize cyclohexanone ethylene ketal as a probe reaction, which has shown its favorable catalytic activity. FT-IR, XRD, SEM, N2 adsorption–desorption isotherms and TG/DTA were used to characterize its composition, structure, morphology, stability and toleration for thermal in order to further prepare the catalyst with effective performance. Moreover, we have also explored the optimized conditions of carrying out the probe reaction by orthogonal experiments. The optimized conditions were as follows: fixing cyclohexanone consumption was 0.02 mol, n(cyclohexanone):n(ethylene glycol) = 1:1.3, the mass ratio of the catalyst to total reactant was 0.2 %, cyclohexane dosage was 4 mL, and the reaction time was 75 min. The yield of the acetals and ketones could reach 54.9 ~ 83.5 % under the optimum conditions. In addition, H6P2W18O62/Cu3(BTC)2 exhibited good reusability and the approaches above may enable rational design of advanced and environmental-friendly MOF-based catalysts.

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References

  1. Li G-X, Ding Y, Wang J-M, Wang X-L, Suo J-S (2007) J Mol Catal A 262:67–76

    Article  CAS  Google Scholar 

  2. Heravi MM, Sadjadi S (2009) J Iran Chem Soc 6:1–54

    Article  CAS  Google Scholar 

  3. Kozhevnikov IV (2009) J Mol Catal A 305:104–111

    Article  CAS  Google Scholar 

  4. Chen T, Che Y-C, Zhang Y, Zhang J-M, Wang F, Wang Z-Z (2014) J Porous Mater 21:495–502

    Article  CAS  Google Scholar 

  5. Sun C-Y, Liu S-X, Liang D-D, Shao K-Z, Ren Y-H, Su Z-M (2009) J Am Chem Soc 131:1883–1888

    Article  CAS  Google Scholar 

  6. Okumura K, Ito S, Yonekawa M, Nakashima A, Niwa M (2009) Top Catal 52:649–656

    Article  CAS  Google Scholar 

  7. Briand LE, Baronettib GT, Thomas HJ (2003) Appl Catal A Gen 256:37–50

    Article  CAS  Google Scholar 

  8. Hamidipour L, Farzaneh F (2013) Reac Kinet Mech Cat 109:67–75

    Article  CAS  Google Scholar 

  9. Bandosz TJ, Petit C (2011) Adsorption 17:5–16

    Article  CAS  Google Scholar 

  10. Kumar P, Deep A, Paul AK, Bharadwaj LM (2014) J Porous Mater 21:99–104

    Article  CAS  Google Scholar 

  11. Wee LH, Bajpe SR, Janssens N, Houthoofd K, Martens JA et al (2010) Chem Commun 46:8186–8188

    Article  CAS  Google Scholar 

  12. Low JJ, Benin AI, Jakubczak P, Abrahamian JF, Faheem SA, Willis RR (2009) J Am Chem Soc 131:15834–15842

    Article  CAS  Google Scholar 

  13. Zamaro JM, Pérez NC, Miró EE, Casado C, Seoane B, Téllez C, Coronas J (2012) Chem Eng J 195–196:180–187

    Article  Google Scholar 

  14. Wang Z-Y, Wang J-J, Li M-Y, Sun K-H, Liu C-J (2014) Sci Rep 4:5939

    CAS  Google Scholar 

  15. Zhou H-C, Long JR, Yaghi OM (2012) Chem Rev 112:673–674

    Article  CAS  Google Scholar 

  16. Zang Y-D, Shi J, Zhao X-M, Kong L-C, Zhang F-M, Zhong Y-J (2013) Reac Kinet Mech Cat 109:77–89

    Article  CAS  Google Scholar 

  17. Chui SS-Y, Lo SM-F, Charmant JPH, Orpen AG, Williams LD (1999) Science 283:1148–1150

    Article  CAS  Google Scholar 

  18. Yang S-J, Huang YK, Yu L (2011) Adv Mater Res 284:2374–2379

    Article  Google Scholar 

  19. Pawar RR, Jadhav SV, Bajaj HC (2014) Chem Eng J 235:61–66

    Article  CAS  Google Scholar 

  20. Lyon DK, Miller WK, Novet T (1991) J Am Chem Soc 113:7209–7221

    Article  CAS  Google Scholar 

  21. Schlichte K, Kratzke T, Kaskel S (2004) Microporous Mesoporous Mater 73:81–88

    Article  CAS  Google Scholar 

  22. Alaerts L, Seguin E, Poelman H, Jacobs PA (2006) Chem Eur J 12:7353–7363

    Article  CAS  Google Scholar 

  23. Juan-Alcañiz J, Ramos-Fernandez EV, Lafont U, Gascon J, Kapteijn F (2010) J Catal 269:229–241

    Article  Google Scholar 

  24. Chowdhury P, Bikkina C, Meister D, Dreisbach F, Gumma S (2009) Microporous Mesoporous Mater 117:406–413

    Article  CAS  Google Scholar 

  25. Li L, Liu X-L, Hu B (2013) J Mater Chem A 1:10292–10299

    Article  CAS  Google Scholar 

  26. Lin S, Song Z-L, Li P, Liu C-B (2014) Microporous Mesoporous Mater 193:27–34

    Article  CAS  Google Scholar 

  27. Li S, Du C-C, Zhao D-F, Liu H-F, Wang Y-Q (2014) J Porous Mater. doi:10.1007/s10934-014-9842-3

    Google Scholar 

  28. Bielanski A, Lubanska A (2004) J Mol Catal A 224:179–187

    Article  CAS  Google Scholar 

  29. Yang L-N, Qi Y-T, Yuan X-D, Shen J, Kim J (2005) J Mol Catal A 229:199–205

    Article  CAS  Google Scholar 

  30. Fan Z-L, Wang X-R, Li G-X (2012) Chin J Mol Catal 26:32–38

    Google Scholar 

  31. Uemura T, Kadowaki Y, Kim CR, Fukushima T (2011) Chem Mater 23:1736–1741

    Article  CAS  Google Scholar 

  32. Baronetti G, Briand L, Sedran U (1998) Appl Catal A Gen 172:265–272

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the Natural Science Foundation of Hubei Province (No. 2014CFA131) and Hubei Key Laboratory of Pollutant Analysis & Reuse Technology (No. KL2013M08, KL2013G01).

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Authors and Affiliations

  1. Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, Hubei Collaborative Innovation Center for Rare Metal Chemistry, College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi, 435002, China

    Xiaoxia Liu, Jing Luo, Tingquan Sun & Shuijin Yang

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  1. Xiaoxia Liu
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  2. Jing Luo
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  3. Tingquan Sun
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  4. Shuijin Yang
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Correspondence to Shuijin Yang.

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Liu, X., Luo, J., Sun, T. et al. A simple approach to the preparation of H6P2W18O62/Cu3(BTC)2 (BTC = 1,3,5-benzenetricarboxylate) and its catalytic performance in the synthesis of acetals/ketals. Reac Kinet Mech Cat 116, 159–171 (2015). https://doi.org/10.1007/s11144-015-0877-5

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  • DOI: https://doi.org/10.1007/s11144-015-0877-5

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