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Production of propylene from ethanol over ZSM-5 co-modified with zirconium and phosphorus

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Abstract

Production of propylene from ethanol was studied over ZSM-5 co-modified with zirconium and phosphorus (P/Zr/ZSM-5). XRD and NH3-TPD were used to characterize P/Zr/ZSM-5 together with H-ZSM-5 and the zirconium modified ZSM-5 (Zr/ZSM-5) for comparison. It was found that the concentration of strong acid sites on P/Zr/ZSM-5 was significantly reduced by the impregnation of phosphorus into Zr/ZSM-5. In the ethanol-to-propylene reaction, P/Zr/ZSM-5 exhibited a better catalytic performance than H-ZSM-5 and Zr/ZSM-5. The in situ UV–Vis spectrum of the ethanol adsorbed P/Zr/ZSM-5 revealed that the species of non desorbed aromatics were hardly produced and thus the formation of carbonaceous deposits was inhibited by the phosphorus modification.

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Authors and Affiliations

  1. Research Institute for Innovation in Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), 16-1, Onogawa, Ibaraki, Tsukuba, 305-8569, Japan

    Zhaoxia Song, Atsushi Takahashi & Tadahiro Fujitani

  2. College of Life Science, Dalian Nationalities University, Dalian, 116600, China

    Zhaoxia Song & Cheng Chen

  3. School of Chemical Engineering, Dalian University of Technology (DLUT), Dalian, 116024, China

    Wei Liu

Authors
  1. Zhaoxia Song
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  2. Wei Liu
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  3. Cheng Chen
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  4. Atsushi Takahashi
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  5. Tadahiro Fujitani
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Correspondence to Wei Liu.

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Song, Z., Liu, W., Chen, C. et al. Production of propylene from ethanol over ZSM-5 co-modified with zirconium and phosphorus. Reac Kinet Mech Cat 109, 221–231 (2013). https://doi.org/10.1007/s11144-013-0546-5

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  • DOI: https://doi.org/10.1007/s11144-013-0546-5

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