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Butene catalytic cracking to ethylene and propylene on fluorinated ZSM-5-based catalyst

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Abstract

In this paper, fluorine-containing ZSM-5 catalysts were first prepared and applied for butene catalytic cracking. Fluorinated ZSM-5 was obtained by treating the ZSM-5 zeolite with NH4F solutions at 85 °C. XRD showed that the intrinsic mordenite framework inverted structure of ZSM-5 zeolite was preserved and the corresponding crystallinity remained unchanged. The N2 adsorption/desorption measure indicated the generation of a number of new micropores. The experiment of butene catalytic cracking showed that catalytic performances can be greatly improved after fluorination treatment. The highest yield of ethylene plus propylene was obtained when the treated concentration of NH4F solution is 0.1 M.

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Acknowledgments

This work was sponsored by West Light Foundation of The Chinese Academy of Sciences, Science and Technique Program of Lanzhou City, Science-Technology Foundation for Middle-Aged and Young Scientist of Gansu Province, and Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, Xinjiang University (XJDX0908-2011-03).

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Authors and Affiliations

  1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China

    Zhicheng Tang, Peng Zhang, Weiliang Han & Gongxuan Lu

  2. Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, Xinjiang University, Urumqi, Xinjiang, 830046, China

    Jiangyin Lu

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  1. Zhicheng Tang
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  2. Peng Zhang
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  3. Weiliang Han
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  4. Gongxuan Lu
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Correspondence to Zhicheng Tang.

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Tang, Z., Zhang, P., Han, W. et al. Butene catalytic cracking to ethylene and propylene on fluorinated ZSM-5-based catalyst. Reac Kinet Mech Cat 108, 231–239 (2013). https://doi.org/10.1007/s11144-012-0512-7

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  • DOI: https://doi.org/10.1007/s11144-012-0512-7

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