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Synthesis of New Crystalline Pu(V) Compounds from Solutions: V. Crystal Structure of [Co(NH3)6][PuO2(C2O4)2] · 3H2O

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Abstract

The compound [Co(NH3)6][PuO2(C2O4)2] · 3H2O was studied by single crystal X-ray diffraction. The structure contains dimeric complex anions [PuO2(C2O4)2] 6−2 in which the coordination polyhedra of the Pu atoms are distorted pentagonal bipyramids sharing a common equatorial edge. In going from [Co(NH3)6] · [NpO2(C2O4)2] · 3H2O to [Co(NH3)6][PuO2(C2O4)2] · 3H2O, the An-O distances, both axial (in the actinyl group) and equatorial, decrease virtually isotropically.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    M. S. Grigor'ev, N. N. Krot & A. A. Bessonov

  2. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, Moscow, Russia

    M. Yu. Antipin

Authors
  1. M. S. Grigor'ev
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  2. M. Yu. Antipin
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  3. N. N. Krot
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  4. A. A. Bessonov
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Translated from Radiokhimiya, Vol. 47, No. 5, 2005, pp. 419–422.

Original Russian Text Copyright © 2005 by Grigor'ev, Antipin, Krot, Bessonov.

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Grigor'ev, M.S., Antipin, M.Y., Krot, N.N. et al. Synthesis of New Crystalline Pu(V) Compounds from Solutions: V. Crystal Structure of [Co(NH3)6][PuO2(C2O4)2] · 3H2O. Radiochemistry 47, 460–463 (2005). https://doi.org/10.1007/s11137-005-0118-2

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  • DOI: https://doi.org/10.1007/s11137-005-0118-2

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