Abstract
Hybrid metal–semiconductor nanoparticles consisting of silver nanoparticle cores (AgNPs) coated with a layer of CdSe quantum dots (QDs) have been studied by Raman spectroscopy. The hybrid nanoparticles were prepared via electrostatic interaction by mixing aqueous suspensions of QDs and AgNPs, where opposite charges on the AgNPs and QDs surfaces were induced by opportunely selected capping agents. Assemblies of such hybrid nanoparticles show an increased intensity of the Raman spectrum of up to 500 times, when compared to that of the sole QDs. This enhancement is attributed to the SERS effect (Surface-enhanced Raman scattering). Such enhancement of the Raman modes suggests several opportunities for further research, both in imaging and sensing applications.
References
Aldana J, Wang YA, Peng X (2001) Photochemical instability of CdSe nanocrystals coated by hydrophilic thiols. J Am Chem Soc 123:8844–8850. doi:10.1021/ja016424q
Atwater HA, Polman A (2010) Plasmonics for improved photovoltaic devices. Nat Mater 9:205–213. doi:10.1038/nmat2629
Brown MD, Suteewong T, Kumar RSS et al (2011) Plasmonic dye-sensitized solar cells using core-shell metal-insulator nanoparticles. Nano Lett 11:438–445. doi:10.1021/nl1031106
Chursanova MV, Dzhagan VM, Yukhymchuk VO et al (2009) Nanostructured silver substrates with stable and universal SERS properties: application to organic molecules and semiconductor nanoparticles. Nanoscale Res Lett 5:403–409. doi:10.1007/s11671-009-9496-2
Dzhagan VM, Lokteva I, Valakh MY et al (2009) Spectral features above LO phonon frequency in resonant Raman scattering spectra of small CdSe nanoparticles. J Appl Phys 106:084318. doi:10.1063/1.3248357
Faulds K, Littleford RE, Graham D et al (2004) Comparison of surface-enhanced resonance Raman scattering from unaggregated and aggregated nanoparticles. Anal Chem 76:592–598. doi:10.1021/ac035053o
Gouadec G, Colomban P (2007) Raman spectroscopy of nanomaterials: how spectra relate to disorder, particle size and mechanical properties. Prog Cryst Growth Charact Mater 53:1–56. doi:10.1016/j.pcrysgrow.2007.01.001
Han XX, Zhao B, Ozaki Y (2009) Surface-enhanced Raman scattering for protein detection. Anal Bioanal Chem 394:1719–1727. doi:10.1007/s00216-009-2702-3
Haridas M, Tripathi LN, Basu JK (2011) Photoluminescence enhancement and quenching in metal-semiconductor quantum dot hybrid arrays. Appl Phys Lett 98:063305. doi:10.1063/1.3553766
Hugall JT, Baumberg JJ, Mahajan S (2009) Surface-enhanced Raman spectroscopy of CdSe quantum dots on nanostructured plasmonic surfaces. Appl Phys Lett 95:141111. doi:10.1063/1.3243982
Kawai M, Yamamoto A, Matsuura N, Kanemitsu Y (2008) Energy transfer in mixed CdSe and Au nanoparticle monolayers studied by simultaneous photoluminescence and Raman spectral measurements. Phys Rev B. doi:10.1103/PhysRevB.78.153308
Khanal BP, Pandey A, Li L et al (2012) Generalized synthesis of hybrid metal-semiconductor nanostructures tunable from the visible to the infrared. ACS Nano 6:3832–3840. doi:10.1021/nn204932m
Kolny J, Kornowski A, Weller H (2002) Self-organization of cadmium sulfide and gold nanoparticles by electrostatic interaction. Nano Lett 2:361–364. doi:10.1021/nl0156843
Kumar A, Chaudhary V (2007) Optical and photophysical properties of Ag/CdS nanocomposites—an analysis of relaxation kinetics of the charge carriers. J Photochem Photobiol, A 189:272–279. doi:10.1016/j.jphotochem.2007.02.013
Lilly GD, Lee J, Kotov N a (2010) “Cloud” assemblies: quantum dots form electrostatically bound dynamic nebulae around large gold nanoparticles. Phys Chem Chem Phys 12:11878–11884. doi:10.1039/c0cp00186d
Lu L, Xu X-L, Liang W-T, Lu H-F (2007) Raman analysis of CdSe/CdS core-shell quantum dots with different CdS shell thickness. J Phys: Condens Matter 19:406221. doi:10.1088/0953-8984/19/40/406221
Mandal S, Bonifacio A, Zanuttin F et al (2010) Synthesis and multidisciplinary characterization of polyelectrolyte multilayer-coated nanogold with improved stability toward aggregation. Colloid Polym Sci 289:269–280. doi:10.1007/s00396-010-2343-2
Marsich L, Bonifacio A, Mandal S et al (2012) Poly-l-lysine-coated silver nanoparticles as positively charged substrates for surface-enhanced Raman scattering. Langmuir 28:13166–13171. doi:10.1021/la302383r
Milekhin a G, Sveshnikova LL, Duda T a et al (2009) Surface enhanced Raman scattering by CdS quantum dots. JETP Lett 88:799–801. doi:10.1134/S0021364008240053
Milekhin AG, Yeryukov N a, Sveshnikova LL et al (2012) Raman scattering for probing semiconductor nanocrystal arrays with a low areal density. J Phys Chem C 116:17164–17168. doi:10.1021/jp210720v
Neto ESF, Dantas NO, Da Silva SW et al (2010) Confirming the lattice contraction in CdSe nanocrystals grown in a glass matrix by Raman scattering. J Raman Spectrosc 41:1302–1305. doi:10.1002/jrs.2565
Noginov MA, Zhu G, Belgrave AM et al (2009) Demonstration of a spaser-based nanolaser. Nature 460:1110–1112. doi:10.1038/nature08318
Roca E, Trallero-Giner C, Cardona M (1994) Polar optical vibrational modes in quantum dots. Phys Rev B 49:13704–13711. doi:10.1103/PhysRevB.49.13704
Rodriguez-Lorenzo L, Fabris L, Alvarez-Puebla RA (2012) Multiplex optical sensing with surface-enhanced Raman scattering: a critical review. Anal Chim Acta 745:10–23. doi:10.1016/j.aca.2012.08.003
Shan G, Xu L, Wang G, Liu Y (2007) Enhanced Raman scattering of ZnO quantum dots on silver colloids. J Phys Chem C 111:3290–3293. doi:10.1021/jp066070v
Sharma B, Frontiera RR, Henry A-I et al (2012) SERS: materials, applications, and the future—review article. Mater Today 15:16–25
Song J-H, Atay T, Shi S et al (2005) Large enhancement of fluorescence efficiency from CdSe/ZnS quantum dots induced by resonant coupling to spatially controlled surface plasmons. Nano Lett 5:1557–1561. doi:10.1021/nl050813r
Sousa F, Mandal S, Garrovo C et al (2010) Functionalized gold nanoparticles: a detailed in vivo multimodal microscopic brain distribution study. Nanoscale 2:2826–2834. doi:10.1039/c0nr00345j
Sun Z, Wang C, Yang J et al (2008) Nanoparticle metal-semiconductor charge transfer in ZnO/PATP/Ag assemblies by surface-enhanced Raman spectroscopy. J Phys Chem C 112:6093–6098. doi:10.1021/jp711240a
Tanaka A, Onari S, Arai T (1992) Raman scattering from CdSe microcrystals embedded in a germanate glass matrix. Phys Rev B 45:6587–6592. doi:10.1103/PhysRevB.45.6587
Thakur P, Joshi SS, Kapoor S, Mukherjee T (2009) Fluorescence behavior of cysteine-mediated Ag@CdS nanocolloids. Langmuir 25:6377–6384. doi:10.1021/la8042507
Venugopal R, Lin P-I, Liu C–C, Chen Y-T (2005) Surface-enhanced Raman scattering and polarized photoluminescence from catalytically grown CdSe nanobelts and sheets. J Am Chem Soc 127:11262–11268. doi:10.1021/ja044270j
Wang Y, Li M, Jia H et al (2006) Optical properties of Ag/CdTe nanocomposite self-organized by electrostatic interaction. Spectrochim Acta Part A Mol Biomol Spectrosc 64:101–105. doi:10.1016/j.saa.2005.07.003
Wang Y, Ruan W, Zhang J et al (2009) Direct observation of surface-enhanced Raman scattering in ZnO nanocrystals. J Raman Spectrosc 40:1072–1077. doi:10.1002/jrs.2241
Yang D, Wang W, Chen Q et al (2008) Electrostatic assembles and optical properties of Au–CdTe QDs and Ag/Au–CdTe QDs. Physica E 40:3072–3077. doi:10.1016/j.physe.2008.04.003
Yu WW, Qu L, Guo W, Peng X (2003) Experimental determination of the extinction coefficient of CdTe, CdSe, and CdS nanocrystals. Chem Mater 15:2854–2860. doi:10.1021/cm034081k
Zhang Y, Hong H, Myklejord DV, Cai W (2011) Molecular imaging with SERS-active nanoparticles. Small 7:3261–3269. doi:10.1002/smll.201100597
Acknowledgments
A.B. is grateful to Fondo Trieste for partial financial support. The authors are grateful to Luca Cozzarini for insight into experimental details.
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Lughi, V., Bonifacio, A., Barbone, M. et al. Surface-enhanced Raman effect in hybrid metal–semiconductor nanoparticle assemblies. J Nanopart Res 15, 1663 (2013). https://doi.org/10.1007/s11051-013-1663-9
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DOI: https://doi.org/10.1007/s11051-013-1663-9