Abstract
The composite films of poly (ether ether ketone) (PEEK) filled with different proportions of graphene oxide (GO) nanosheets were prepared by the cast method. The tribological behaviors of the composite films under boundary lubrication (water and liquid paraffin oil lubrication) were investigated and compared with that under dry sliding on an UMT-2 friction and wear machine, by running a steel sphere against the composite films. The results were as follows: GO nanosheets as the filler greatly improve the wear resistance of PEEK under boundary lubrication, though the composites show a different dependence of wear resistance on the filler content. Scanning electron microscopy and optical microscopy performed to analyze the wear scar surfaces after friction confirmed that the outstanding lubrication performance of GO could be attributed to their small size and extremely thin laminated structure, which allow the GO to easily enter the contact area, thereby preventing the rough surfaces from coming into direct contact.
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References
Balaji V, Tiwari AN, Goyal RK (2011) Fabrication and properties of high performance PEEK/Si3N4 nanocomposites. J Appl Polym Sci 119:311–318
Davim JP, Cardoso R (2009) Effect of the reinforcement (carbon or glass fibres) on friction and wear behaviours of the PEEK against steel surface at long dry sliding. Wear 266:795–799
Diez-Pascual AM, Guan JW, Simard B, Gomez-Fatou MA (2011) Poly(phenylene sulphide) and poly(ether ether ketone) composites reinforced with single-walled carbon nanotube buckypaper: I-Structure, thermal stability and crystallization behaviour. Compos Part A 43:997–1006
Diez-Pascual AM, Naffakh M, Marco C, Ellis G, Gomez-Fatou MA (2012) High-performance nanocomposites based on polyetherketones. Prog Mater Sci 57:1106–1190
Dikin DA, Stankovich S, Zimney EJ, Piner RD, Dommett GHB, Evmenenko G, Nguyen ST, Ruoff RS (2007) Preparation and characterization of graphene oxide paper. Nature 448:457–460
Du X, Yu ZZ, Dasari A, Ma J, Mo M, Meng Y, Mai YW (2008) New method to prepare graphite nanocomposites. Chem Mater 20:2066–2068
Gomez-Navarro C, Burghard M, Kern K (2008) Elastic properties of chemically derived single graphene sheets. Nano Lett 8:2045–2049
Guo HL, Wang XF, Qian QY, Wang FB, Xia XH (2009) A green approach to the synthesis of graphene nanosheets. ACS Nano 3:2653–2659
Han Y, Lu Y (2009) Characterization and electrical properties of conductive polymer/colloidal graphite oxide nanocomposites. Comp Sci Technol 69:1231–1237
Hou XH, Shan CX, Choy KL (2008) Microstructures and tribological properties of PEEK-based nanocomposite coatings incorporating inorganic fullerene-like nanoparticles. Surf Coat Technol 202:2287–2291
Kotov NA, Dekany I, Fendler JH (1996) Ultrathin graphite oxide–polyelectrolyte composites prepared by self-assembly: Transition between conductive and non-conductive states. Adv Mater 8:637–641
Li YQ, Wang QH, Wang TM, Pan GQ (2012) Preparation and tribological properties of graphene oxide/nitrile rubber nanocomposites. J Mater Sci 47:730–738
Lin JS, Wang LW, Chen GH (2011) Modification of graphene platelets and their tribological properties as a lubricant additive. Tribol Lett 41:209–215
Liu PG, Gong KC, Xiao P, Xiao M (2000) Preparation and characterization of poly(vinyl acetate)-intercalated graphite oxide nanocomposite. J Mater Chem 10:933–935
Liu S, Ou JF, Li ZP, Yang SR, Wang JQ (2012) Layer-by-layer assembly and tribological property of multilayer ultrathin films constructed by modified graphene sheets and polyethyleneimine. Appl Surf Sci 258:2231–2236
Marcano DC, Kosynkin DV, Berlin JM, Sinitskii A (2010) Improved synthesis of graphene oxide. ACS Nano 4:4806–4814
Matsuo Y, Tahara K, Sugie Y (1997) Structure and thermal properties of poly(ethylene oxide)-intercalated graphite oxide. Carbon 35:113–120
Nguyen DA, Lee YR, Raghu AV, Jeong HM, Shin CM, Kim BK (2009) Morphological and physical properties of a thermoplastic polyurethane reinforced with functionalized graphene sheet. Polym Int 58:412–417
Peterson MB, Murray SF, Florek JJ (1959) Consideration of lubricants for temperatures above 1000 F. Tribol Trans 2:225–234
Ren PG, Yan DX, Chen T, Zeng BQ, Li ZM (2011) Improved properties of highly oriented graphene/polymer nanocomposites. J Appl Polym Sci 121:3167–3174
Rong CR, Ma G, Zhang SL, Song L, Chen Z, Wang GB, Ajayan PM (2010) Effect of carbon nanotubes on the mechanical properties and crystallization behavior of poly(ether ether ketone). Compos Sci Technol 70:380–386
Song HJ, Jia XH, Li N, Yang XF, Tang H (2012a) Synthesis of alpha-Fe2O3 nanorod/graphene oxide composites and their tribological properties. J Mater Chem 22:895–902
Song HJ, Li N, Li YJ, Min CY, Wang Z (2012b) Preparation and tribological properties of graphene/poly(ether ether ketone) nanocomposites. J Mater Sci 47:6436–6443
Tai ZX, Yan XB, Xue QJ (2012a) Shape-alterable and -recoverable graphene/polyurethane bi-layered composite film for supercapacitor electrode. J Power Sources 213:350–357
Tai ZX, Chen YF, An YF, Yan XB, Xue QJ (2012b) Tribological behavior of UHMWPE reinforced with graphene oxide nanosheets. Tribol Lett 46:55–63
Verdejo R, Barroso-Bujans F, Rodriguez-Perez MA, Sajab JA, Lopez-Manchado MA (2008) Functionalized graphene sheet filled silicone foam nanocomposites. J Mater Chem 18:2221–2226
Werner P, Altstädt V, Jaskulka R, Jacobs O (2004) Tribological behaviour of carbon-nanofibre-reinforced poly(ether ether ketone). Wear 257:1006–1014
Wu HL, Ma CC, Liu FY, Chen CY, Lee SJ (2006) Preparation and characterization of poly(ether sulfone)/sulfonated poly(ether ether ketone) blend membranes. Eur Polym J 42:1688–1695
Wu JH, Yen MS, Chen CW, Kuo MC, Tsai FK, Kuo JS, Yang LH, Huang JC (2012) Isothermal crystallization behavior of nano-alumina particles-filled poly(ether ether ketone) composites. J Appl Polym Sci 125:494–504
Xu J, Hu Y, Song L, Wang Q, Fan W, Chen Z (2002) Preparation and characterization of poly(vinyl alcohol)/graphite oxide nanocomposite. Carbon 40:450–451
Yang Y, Wang J, Zhang J, Liu J, Yang X, Zhao H (2009) Exfoliated graphite oxide decorated by PDMAEMA chains and polymer particles. Langmuir 25:11808–11814
Yang XM, Shang SM, Li L (2011) Layer-structured poly(vinyl alcohol)/graphene oxide nanocomposites with improved thermal and mechanical properties. J Appl Polym Sci 120:1355–1360
Zaman I, Kuan HC, Meng QS, Michelmore A, Kawashima N, Pitt T, Zhang LQ, Gouda S, Luong L, Ma J (2012) A facile approach to chemically modified graphene and its polymer nanocomposites. Adv Funct Mater 22:2735–2743
Zhang G, Zhang C, Nardin P, Li WY, Liao H, Coddet C (2008) Effects of sliding velocity and applied load on the tribological mechanism of amorphous poly-ether-ether-ketone (PEEK). Tribol Int 41:79–86
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This work has been supported by the Natural Science Foundation of China (50903040, 51103065), the Priority Academic Program Development of Jiangsu Higher Education Institutions, and the Foundation of State Key Laboratory of Solid Lubrication (1202).
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Song, HJ., Li, N., Yang, J. et al. Preparation and tribological behaviors of poly (ether ether ketone) nanocomposite films containing graphene oxide nanosheets. J Nanopart Res 15, 1433 (2013). https://doi.org/10.1007/s11051-013-1433-8
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DOI: https://doi.org/10.1007/s11051-013-1433-8