Abstract
A robust functionalized procedure for gold nanorods (Au NR) with mercaptoundecanoic acid (MUA), which are assembled with nanoparticles, has been reported in the present work. The self-assembled nanostructures were characterized by UV–Vis-NIR spectrophotometer and transmission electron microscopy (TEM). Self-assembly procedures, governed by surface chemistry, indicated that chemical reactivity of nanomaterial may contribute in construction of potential nanoscale assemblies. These nanostructures have striking applications as single-molecule detection, plasmonics, and sensing.
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References
Beda J, Herbert K, Richard C (1997) Covalent attachment of hybridizable oligonucleotides to glass supports. Anal Biochem 247:96–101
Connor E, Mwamuka J, Gole A, Murphy C, Wyatt M (2005) Gold nanoparticles are taken up by human cells but do not cause acute cytotoxicity. Small 1:325–327
Fernández JR, Juste JP, García de Abajo FJ, Marzán LML (2006) Seeded growth of submicron au colloids with quadrupole plasmon resonance modes. Langmuir 22:7007–7010
Gole A, Murphy CJ (2005) Polyelectrolyte coated gold nanorods: synthesis, characterization and immobilization. Chem Mater 17:1325–1330
Gupta AK, Gupta M (2005) Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications. Biomaterials 26:3995
Hongwei L, Jason HH (2005) Gold nanorod bioconjugates. Chem Mater 17:4636–4641
Kim S (2004) Near-infrared fluorescent type II quantum dots for sentinel lymph node mapping. Nat Biotechnol 22:93–97
Lin SY, Tsai YT, Chen CC, Lin CM, Chen CH (2004) Two-step functionalization of netural and positively charged thiols onto citrate-stabilized Au nanoparticles. J Phys Chem B 108:2134–2139
Love JC, Estroff LA, Kriebel JK, Nuzzo RG, Whitesides GM (2005) Self-assembled monolayers of thiolates on metals as a form of nanotechnology. Chem Rev 105:1103–1169
Marzán LML (2004) Nanometals—formation and color. Mater Today 7:26–31
McFarland AD, Van Duyne RP (2003) Single silver nanoparticles as real-time optical sensors with zeptomole sensitivity. Nano Lett 3:1057–1062
Mirska D, Schirmer K, Funari SS, Langner A, Dobner B, Brezesinski G (2005) Biophysical and biochemical properties of a binary lipid mixture for DNA transfection. Colloids Surf B 40:51–59
Mirza AZ, Shamshad H (2011) Preparation and characterization of doxorubicin functionalized gold nanoparticles. Eur J Med Chem 46:1857–1860
Nikoobakht B, El-Sayed MA (2001) Evidence for bilayer assembly of cationic surfactants on the surface of gold nanorods. Langmuir 17:6368–6374
Nikoobakht B, El-Sayed MA (2003) Preparation and growth mechanism of gold nanorods (nrs) using seed-mediated growth method. Chem Mater 1957:15
Norman RS, Stone JW, Gole A, Murphy CJ, Sabo-Attwood TL (2008) Targeted photothermal lysis of the pathogenic bacteria, Pseudomonas aeruginosa, with gold nanorods. Nano Lett 8:302
Pierrat S, Zins I, Breivogel A, Snnichsen C (2007) Self-assembly of small gold colloids with functionalized gold nanorods. Nano Lett 7:259–263
Raschke G, Kowarik S, Franzl T, So¨nnichsen C, Klar TA, Feldmann J, Nichtl A, Kurzinger K (2003) Biomolecular recognition based on single gold nanoparticle light scattering. Nano Lett 3:935
Schultz S, Smith DR, Mock JJ, Schultz DA (2000) Single-target molecule detection with nonbleaching multicolor optical immune labels. Proc Natl Acad Sci USA 97:996
Sonnichsen C, Franzl T, Wilk T, von Plessen G, Feldmann J, Wilson O, Mulvaney P (2002) Drastic reduction of plasmon damping in gold nanorods. Phys Rev Lett 88:77402
Torchilin VP (2007) Micellar nanocarriers: pharmaceutical perspectives. Pharm Res 24:1–16
Trindade T, Óbrien P, Pickett NL (2001) Nanocrystalline semiconductors: synthesis, properties, and perspectives. Chem Mater 13:3843
Wang C, Irudayaraj J (2008) Gold Nanorod probes for the detection of multiple pathogens. Small 4:2204–2208
Yan-Juan G, Jinping C, Chun-Chi L, Yun WL, Shuk HC, Wing-T W (2009) Nuclear penetration of surface functionalized gold nanoparticles. Toxicol Appl Pharmacol 237:196–204
Zimmer A (1999) Antisense oligonucleotide delivery with polyhexylcyanoacrylate nanoparticles as carriers. Companion Methods Enzymol 18:286–295
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Mirza, A.Z., Shamshad, H. A versatile approach for the functionalization of gold nanorods and nanoparticles. J Nanopart Res 15, 1404 (2013). https://doi.org/10.1007/s11051-012-1404-5
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DOI: https://doi.org/10.1007/s11051-012-1404-5