Journal of Nanoparticle Research

, Volume 12, Issue 1, pp 319–325

Facile approach to prepare PIPD nano-spheres

Authors

  • Kejing Yu
    • The Key laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, School of Materials Science and TechnologyBeijing University of Chemical Technology
  • Zhongjie Du
    • The Key laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, School of Materials Science and TechnologyBeijing University of Chemical Technology
  • Hangquan Li
    • The Key laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, School of Materials Science and TechnologyBeijing University of Chemical Technology
    • The Key laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, School of Materials Science and TechnologyBeijing University of Chemical Technology
Research Paper

DOI: 10.1007/s11051-009-9616-z

Cite this article as:
Yu, K., Du, Z., Li, H. et al. J Nanopart Res (2010) 12: 319. doi:10.1007/s11051-009-9616-z
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Abstract

Poly(2,6-diimidazo [4,5-b:4′5′-e]pyridinylene-1,4(2,5-dihydroxy) phenylene) (PIPD) was synthesized via polycondensation in phosphorus acid and separated as nano-spheres about 50 nm in diameter. When a heterogeneous additive, acid-treated carbon nanotubes, or calcium carbonate nanoparticles were present during polycondensation, nano-spheres near or larger than 100 nm could be obtained. The morphology of PIPD nano-spheres was observed using transmission and scanning electron microscopy. The thermal behavior and the relative composition of the nano-spheres were characterized using thermal gravimetric analysis. The function of the additives was explored in terms of heterogeneous nucleation. The effect of the solvents used for sphere separation was also considered.

Keywords

PIPDNano-spheresHydrogen bondsNanostructured polymersSynthesis

Copyright information

© Springer Science+Business Media B.V. 2009