Abstract
In this study, mechanochemical processing has been used to manufacture a nanoparticulate powder of ZnO with a controlled particle size and minimal hard agglomeration. The suitability of this ZnO powder for use as either a photocatalyst or an optically transparent UV-filter was evaluated by comparing its optical and photocatalytic properties with those of three commercially available powders that were synthesised by chemical precipitation and flame pyrolysis. The ZnO powder synthesised by mechanochemical processing was found to exhibit high optical transparency and low photocatalytic activity per unit of surface area, which indicates that it is suitable for use in optically transparent UV-filters.
References
Akurati K, Vital A, Fortunato G, Hany R, Nueesch F, Graule T (2007) Flame synthesis of TiO2 nanoparticles with high photocatalytic activity. Solid State Sci 9:247–257
Cullity B (1978) Elements of X-ray diffraction, 2nd edn. Addison-Wesley, Reading
Dodd A, McKinley A, Saunders M, Tsuzuki T (2006) Effect of particle size on the photocatalytic activity of nanoparticulate zinc oxide. J Nanopart Res 8:43–51
Grela M, Coronel M, Colussi A (1996) Quantitative spin-trapping studies of weakly illuminated titanium dioxide sols. Implications of the mechanism of photocatalysis. J Phys Chem 100:16940–16946
Hoffman M, Martin S, Choi W, Bahnemann D (1995) Environmental applications of semiconductor photocatalysis. Chem Revs 95:69–95
Jaeger C, Bard A (1979) Spin trapping and electron spin resonance detection of radical intermediates in the photodecomposition of water at TiO2 particulate Systems. J Phys Chem 83:3146–3152
Janzen E (1971) Spin trapping. Acc Chem Res 4:31–40
Kerker M (1969) The scattering of light, New York: Academic Press
McCormick P, Tsuzuki T, Robinson J, Ding J (2001) Nanopowders synthesized by mechanochemical processing. Adv Mater 13:1008–1010
Readey M, Lee R, Halloran J, Heur A (1990) Processing and sintering of ultrafine MgO-ZrO2 and (MgO, Y2O3)-ZrO2 powders. J Am Ceram Soc 73:1499–1503
Ricci A, Chrétien M, Maretti L, Scaiano J (2003) TiO2 promoted mineralization of organic sunscreen in water suspension and sodium dodecyl sulfate micelles. Photochem Photobiol Sci 2:487–492
Serpone N, Dondi D, Albini A (2007) Inorganic and organic UV filters: their role and efficacy in sunscreens and suncare products. Inorg Chim Acta 360:794–802
Tanaka K, Capule M, Hisanaga T (1991) Effect of crystallinity of TiO2 on its photocatalytic activity. Chem Phys Lett 187:73–76
Tryba B, Toyoda M, Morawski A, Nonaka R, Inagaki M (2007) Photocatalytic activity and OH radical formation on TiO2 in the relation to crystallinity. Appl Catal B 71:163–168
Tsuzuki T, McCormick P (2001) ZnO nanoparticles synthesised by mechanochemical processing. Scr Mater 44:1731–1734
Zhang Z, Wang C, Zakaria R, Ying J (1998) Role of particle size in nanocrystalline TiO2-based photocatalysts. J Phys Chem B 102:10871–10878
Acknowledgments
This research was supported by the Australian Research Council under Linkage Project LP0349177 and was carried out using facilities at the Centre for Microscopy, Characterisation and Analysis, which is supported by University, State and Federal Government funding.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Dodd, A., McKinley, A., Tsuzuki, T. et al. A comparative evaluation of the photocatalytic and optical properties of nanoparticulate ZnO synthesised by mechanochemical processing. J Nanopart Res 10 (Suppl 1), 243–248 (2008). https://doi.org/10.1007/s11051-008-9412-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11051-008-9412-1