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The synthesis and structural characterization of transition metal coordination complexes of coumarilic acid

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Abstract

The coumarilate (coum−) complexes of CoII(1), NiII(2) CuII(3) and ZnII(4) were synthesized and characterized by elemental analysis, magnetic susceptibility, solid-state UV–Vis, FTIR spectra, thermoanalytical TG–DTG/DTA and single-crystal X-ray diffraction methods. It was found that all of the complex structures have 2 mol (coum−) ligand bonded as monoanionic monodentate in the structures of 1 and 2 while they were coordinated to metal cations as monoanionic bidentate in the complexes 3 and 4. There was not any hydrate water in the metal complexes. The complexes of 1 and 2 have four moles of aqua ligand, and the other complexes have two moles. Thermal decomposition of each complex starts with dehydration, and then the decomposition of organic parts goes. The thermal dehydration of the complexes takes place in one (for the compounds of 2, 3, 4) or two (for the compound 1) steps. The decomposition mechanism and the thermal stability of the complexes under investigation were determined on the basis of their structures. Metal oxides were obtained as the final decomposition product.

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Acknowledgements

This work has been supported by Hitit University Scientific Research Unit (Project No: FEF19004.15.005).

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Authors and Affiliations

  1. Department of Chemistry, Hitit University, 19040, Ulukavak/Çorum, Turkey

    Özge Dağlı & Dursun Ali Köse

  2. Scientific and Technological Research Application Center, Sinop University, 57000, Sinop, Turkey

    Onur Şahin

  3. Department of Energy Systems Engineering, Sinop University, 57000, Sinop, Turkey

    Zarife Sibel Şahin

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  1. Özge Dağlı
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  2. Dursun Ali Köse
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  3. Onur Şahin
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  4. Zarife Sibel Şahin
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Correspondence to Dursun Ali Köse.

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Dağlı, Ö., Köse, D.A., Şahin, O. et al. The synthesis and structural characterization of transition metal coordination complexes of coumarilic acid. J Therm Anal Calorim 128, 1373–1383 (2017). https://doi.org/10.1007/s10973-016-6053-y

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  • DOI: https://doi.org/10.1007/s10973-016-6053-y

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