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The calorimetric investigation of the mixing enthalpy of liquid Co–Ni–Zr alloys at 1873 K

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Abstract

The partial mixing enthalpies of zirconium in liquid Co–Ni–Zr alloys have been determined by means of high-temperature isoperibolic calorimeter. The measurements have been performed along the sections x Co/x Ni = 3/1, 1/1, 1/3 in the composition range x Zr = 0–0.50 at 1,873 K. The values of the partial function are negative over the investigated composition range. The limiting partial enthalpies of mixing of undercooled liquid zirconium in liquid Co–Ni alloys are (−140 ± 10) kJ mol−1 (the section x Co/x Ni = 3/1), (−199 ± 11) kJ mol−1 (the section x Co/x Ni = 1/1), and (−193 ± 16) kJ mol−1 (the section x Co/x Ni = 1/3). The integral mixing enthalpies have been calculated by Gibbs–Duhem integration. The calculated values are mainly negative. The obtained experimental results together with literature calorimetric data have been described by a least square fit using the Redlich–Kister–Muggianu polynomial. The integral mixing enthalpy has been calculated over the entire composition range.

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Acknowledgements

This work was supported by the Ministry of Education and Science of Ukraine under the Grant 0112U001245.

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Authors and Affiliations

  1. Metallurgical Department, Donbass State Engineering Academy, Shkadinova Street 72, Kramatorsk, 84313, Ukraine

    Liya A. Dreval, Pavel G. Agraval & Mikhail A. Turchanin

  2. Department of Phase Equilibria, G.V. Kurdyumov Institute for Metal Physics, National Academy of Sciences of Ukraine, 36 Academician Vernadsky Blvd., Kiev-142, 03680, Ukraine

    Tetiana A. Kosorukova & Volodymir G. Ivanchenko

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  1. Liya A. Dreval
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  2. Pavel G. Agraval
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  3. Mikhail A. Turchanin
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  5. Volodymir G. Ivanchenko
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Correspondence to Liya A. Dreval.

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Dreval, L.A., Agraval, P.G., Turchanin, M.A. et al. The calorimetric investigation of the mixing enthalpy of liquid Co–Ni–Zr alloys at 1873 K. J Therm Anal Calorim 119, 747–756 (2015). https://doi.org/10.1007/s10973-014-4202-8

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