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Some thermodynamic aspects of nitrides in materials science

Fluorine bomb calorimetry study

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Abstract

The energies of combustion in fluorine of gallium nitride and indium nitride in wurzite crystalline structure have been measured in a two-compartment calorimetric bomb, and new standard molar enthalpies of formation have been calculated: Δf H m 0(GaN(cr) 298.15 K)= –(163.7±4.2) kJ mol–1 and Δf H m 0(InN(cr) 298.15 K)= –(146.5±4.6) kJ mol–1 . Comparison with the recommended values of the Δf H m 0 nitrides from the literature is also presented.

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  1. Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland, 01-224, Kasprzaka 44/52

    Zięborak-Tomaszkiewicz I.

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Zięborak-Tomaszkiewicz, I. Some thermodynamic aspects of nitrides in materials science. J Therm Anal Calorim 83, 611–615 (2006). https://doi.org/10.1007/s10973-005-7421-1

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