Skip to main content
SpringerLink
Log in

Transparent, thermally stable methyl siloxane hybrid materials using sol-gel synthesized vinyl-methyl oligosiloxane resin

  • Original Paper: Sol-gel and hybrid materials for optical, photonic and optoelectronic applications
  • Published:
Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Abstract

Vinyl-methyl oligosiloxane resin was synthesized by a hydrolytic sol-gel reaction of vinyltriethoxysilane and dimethyldiethoxysilane. Hydrochloric acid was added as a catalyst to promote the hydrolysis of silane monomers to form a highly condensed siloxane resin (Condensation degree = 95 %). The vinyl-methyl oligosiloxane and hydrogen-methyl oligosiloxane resin was then cured by a thermal hydrosilylation reaction with a minimal platinum catalyst content (3 ppm). The increased cross-linking density improved the thermal decomposition temperature and lowered the weight loss at a high temperature. The fabricated methyl-siloxane hybrid material (hybrimer) shows superior thermal stability (decomposition temperature >530 °C), good long-term thermal resistance (300 °C, 20 h) and transparency (92 % at 450 nm, 83 % at 350 nm) in the visible and ultraviolet ranges. Based on these characteristics, the methyl-siloxane hybrimer can be applied to various applications, including thermally stable optical materials.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Schubert U, Husing N, Lorenz A (1995) Chem Mater 7:2010

    Article  Google Scholar 

  2. Schmidt H, Jonschker G, Goedicke S, Mennig M (2000) J Sol-Gel Sci Technol 19:39

    Article  Google Scholar 

  3. Sanchez C, In M (1992) J Non-Cryst Solids 147:1

    Article  Google Scholar 

  4. Vioux A (1997) Chem Mater 9:2292

    Article  Google Scholar 

  5. Buestrich R, Kahlenberg F, Popall M (2001) J Sol-Gel Sci Technol 20:181

    Article  Google Scholar 

  6. Katayama S, Yamada N, Shibata Y, Noda K (2003) J Ceram Soc Japan 111:391

    Article  Google Scholar 

  7. Oubaha M, Etienne P, Calas S, Sempere R, Nedelec JM, Moreau Y (2005) J Non-Cryst Solids 351:2122

    Article  Google Scholar 

  8. Ariga K, Yamauchi Y, Rydzek G, Ji Q, Yonamine Y, Wu KCW, Hill JP (2014) Chem Lett 43:36

    Article  Google Scholar 

  9. Wang B, Liang W, Guo Z, Liu W (2015) Chem Soc Rev 44:336

    Article  Google Scholar 

  10. Kim JS, Yang SC, Kwak SY, Choi YW, Paik KW, Bae BS (2012) J Mater Chem 22:7954

    Article  Google Scholar 

  11. Bae JY, Kim YH, Kim HY, Lim YW, Bae BS (2013) RSC Adv 3:8871

    Article  Google Scholar 

  12. Tao P, Li Y, Siegel RW, Schadler LS (2013) J Appl Polym Sci 130:3785

    Article  Google Scholar 

  13. Norris AW, Bahadur M, Yoshitake M (2005) Proc SPIE 5941:594115

    Google Scholar 

  14. Kim YH, Bae JY, Jin JH, Bae BS (2014) ACS Appl Mater Interfaces 6:3115

    Article  Google Scholar 

  15. Costa F, Fregones D, Agnello S, Cannas M (2011) Glass Technol Part A 54:185

    Google Scholar 

  16. Mosley DW, Khanarian G, Conner DM, Thorsen DL, Zhang T, Wills M (2014) J Appl Polym Sci 131:39824

    Article  Google Scholar 

  17. Degroot JV, Norris AM, Glover SO, Clapp TV (2004) Proc SPIE 5517:116

    Article  Google Scholar 

  18. Bae JY, Kim YH, Kim HY, Kim YB, Jin JH, Bae BS (2015) ACS Appl Mater & Interfaces 7:1035

    Article  Google Scholar 

  19. Sanchez C, In M (1992) J. Non-Cryst Solids 147:1

    Article  Google Scholar 

  20. Brook MA (2000) Organometallic and Polymer Chemistry. Wiley, New York, NY, Ch. 9

    Google Scholar 

  21. Brinker CJ, Scherer GW (1990) Sol-Gel Science. Academic Press, CA, Ch. 3

    Google Scholar 

  22. Livage J (1999) Bull Mater Sci 127:1

    Google Scholar 

  23. Yang SC, Kwak SY, Jin JH, Bae BS (2009) ACS Appl Mater Interfaces 1(7):1585

    Article  Google Scholar 

  24. Eo YJ, Kim JH, Ko JH, Bae BS (2005) J Sol-Gel Sci Technol 53:434

    Google Scholar 

  25. Gualandris V, Babonneau F, Janicke MT, Chmelka BF (1998) J Sol-Gel Sci Technol 12:78

    Google Scholar 

  26. Nyczyk A, Paluszkiewicz C, Hasik M, Cypriyk M, Pospiech P (2012) Vib Spectrosc 59:1

    Article  Google Scholar 

  27. Bae JY, Kim HY, Lim YW, Kim YH, Bae BS (2016) RSC Adv 6:26826

    Article  Google Scholar 

  28. Harrod J, Yun S (1987) Organometallics 6:1381

    Article  Google Scholar 

  29. Chalk A, Harrod J (1965) J Am Chem Soc 87:16

    Article  Google Scholar 

  30. Israeli Y, Cavezzan J, Lacoste J (1992) Polym Degrad Stab 98:720

    Google Scholar 

  31. Conley RT (1970) Thermal Stability of Polymers. Marcel Dekker, New York, NY, Ch. 3

    Google Scholar 

  32. Jin JH, Yang SC, Bae BS (2011) Polym Chem 2:168

Download references

Acknowledgments

This work was supported by Wearable Platform Materials Technology Center (WMC) funded by the National Research foundation of Korea (NRF) Grant of the Korea government (MSIP) (NRF-2016R1A5A1009926). This work was also supported by a grant from the Korea Evaluation Institute of Industrial Technology (Project number : 10051337). We are gratefully thank to the Korea Basic Science Institute (KBSI) for 29Si NMR spectra measurement.

Author information

Authors and Affiliations

  1. Laboratory of Optical Materials and Coating (LOMC), Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), 305-701, Daejeon, Republic of Korea

    Jun-Young Bae, Junho Jang & Byeong-Soo Bae

Authors
  1. Jun-Young Bae
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Junho Jang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Byeong-Soo Bae
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Byeong-Soo Bae.

Ethics declarations

Conflict of interest

The authors declare that they have no competing interests.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bae, JY., Jang, J. & Bae, BS. Transparent, thermally stable methyl siloxane hybrid materials using sol-gel synthesized vinyl-methyl oligosiloxane resin. J Sol-Gel Sci Technol 82, 253–260 (2017). https://doi.org/10.1007/s10971-016-4262-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10971-016-4262-2

Keywords

Search

Navigation