Abstract
Nanocomposites based on zinc oxide and ytterbium oxide nanocrystals with Yb atomic content varied from 0.5 up to 6 % were synthesized from alcohol solutions followed by thermal annealing in air. The prepared samples were characterized by means of the X-ray diffraction, transmission electron microscopy and photoluminescence spectroscopy. A sharp photoluminescence line of Yb3+ ions was detected at 983 nm and it was stronger for the samples thermally annealed at 750 °C. The intensity of Yb3+ photoluminescence was found to be slightly depended on Yb concentration and to exhibit a square root dependence on excitation intensity. The experimental results are explained by assuming energy transfer from the photoexcited zinc oxide nanocrystals to ytterbium oxide nanoparticles on their surface. The obtained results indicate possible applications of Yb-doped zinc oxide nanostructures in optoelectronics devices and as infrared biomarkers.
Graphical Abstract
Similar content being viewed by others
References
Wang ZL (2004) J Phys Cond Mat 16:R829–R858
Guillen C, Herrero J (2011) Thin Sol Films 520:1–17
Zimmler MA, Capasso F, Muller S, Ronning C (2010) Semicond. Sci Technol 25:024001
Kumar ES, Singh Sh, Ramachandra Rao MS (2014) Zinc Oxide: The Versatile Material with an Assortment of Physical Properties. In: Ramachandra Rao MS, Okadam T (eds) "ZnO Nanocrystals and Allied Materials", Springer Ser. Mat. Sci, Springer India, New Delhi
Dong J, Bass M, Mao Y, Deng P, Gan F (2003) J Opt Soc Am. B 20:1975–1979
Cascales C, Serrano MD, Esteban-Betegón F, Zaldo C, Peters R, Petermann K, Huber G, Ackermann L, Rytz D, Dupré C, Rico M, Liu J, Griebner U, Petrov V (2006) Phys Rev B 74:174114
Shestakov MV, Baranov AN, Tikhomirov VK, Zubavichus YV, Kuznetsov AS, Veligzhanin AA, Kharin AYu, Rösslhuber R, Timoshenko VYu, Moshchalkov VV (2102) RSC Advances 2:8783–8788
Dexter DL (1957) Phys Rev 108:630–633
Van Dijken A, Meulenkamp EA, Vanmaekelbergh D, Meijerink A (2000) J Lumin 90:123–128
Kovalenko AA, Baranov AN, Panin GN (2008) Russ J Inorg Chem 53:1546–1551
Baranov AN, Kapitanova OO, Panin GN, Kang TV (2008) Russ J Inorg Chem 53:1366–1370
Luo Q, Qiao X, Fan X, Zhang X (2011) Optics Lett 36:2767–2769
Dexter DL (1953) J Chem Phys 21:836–850
Acknowledgment
This work was supported by the Russian Foundation for Basic Research (Grant No. 14-03-00721_a)
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no competing interests.
Electronic supplementary material
Rights and permissions
About this article
Cite this article
Shalygina, О.А., Nazarov, I.V., Baranov, A.V. et al. Structure and photoluminescence properties of zinc oxide/ytterbium oxide nanocomposites. J Sol-Gel Sci Technol 81, 333–337 (2017). https://doi.org/10.1007/s10971-016-4258-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10971-016-4258-y