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Micro structural investigations on TNT and PETN incorporated silica xerogels

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Abstract

Silica xerogels incorporated with trinitrotoluene (TNT) and pentaerythritoltetranitrate (PETN) were synthesized using sol–gel method. Tetramethoxysilane was used as precursor for silica. TNT and PETN content in the resulted explosive/silica xerogel was varied ranging from 50 to 90%. Infra red spectra showed that explosives were retained in the silica xerogel matrix. Transmission electron microscopy (TEM) reveal that explosives particles were uniformly distributed in xerogel matrix and the size of the PETN and TNT particles are in the range 15–18 nm. Small angle x-ray scattering showed that the sizes of the pores in the silica matrix are in the range 25–13 nm. The particles of TNT and PETN occupy the pores in the matrix resulting in gradual reduction of pore-size affecting the surface characteristics of the pore-matrix interface. Understanding of the structure of aggregates of small particles thus produced could be useful to explain the properties shown by the fine explosives. Our study suggests that particle size of explosives in the nanometer range can be achieved using the sol–gel method.

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References

  1. Moulard H (1989) In: Proceedings of 9th Symposium (International) on Detonation, Portland, USA, p 18–24

  2. Kneisl P, Brock KA (2006) US Patent Application: 20060272756, Class: 149092000

  3. Pillai AGS, Sanhavi RR, Dayanandan CR, Joshi MM, Velapure SP, Singh A (2001) Propellants Explos Pyrotech 26:226–228

    Article  CAS  Google Scholar 

  4. Cave GA, Krotinger NJ, Jiccaleb JD (1949) Ind Eng Chem 41(6):1286–1290

    Article  CAS  Google Scholar 

  5. Patil MN, Gore GM, Pandit AB (2008) Ultrason Sonochem 15(3):177–187

    Article  PubMed  CAS  Google Scholar 

  6. Teipel U, Forter-Barth U, Gerber P, Kraose HH (1997) Propellants Explos Pyrotech 22:165–169

    Article  CAS  Google Scholar 

  7. Simpson R, Lee R, Tillotson T, Hrubesh L, Swansiger R, Fox G (2005) United States Patent 6893518

  8. Tilloston TM, Hrubesh LW, Simpson RL, Lee RS, Swansiger RW, Simpson LR (1998) J Non-Cryst Solids 225:358–363

    Article  ADS  Google Scholar 

  9. Schmidt PW, Height R (1960) Acta Cryst 13:480–483

    Article  CAS  Google Scholar 

  10. Clarkson J, Smith WE, Batchelder DN, Smith DA, Coatsc AM (2003) J of Mol Struct 648:203–214

    Article  ADS  CAS  Google Scholar 

  11. Wagh PB, Ingale SV (2002) Ceram Int 28:43–50

    Article  CAS  Google Scholar 

  12. Makashir PS, Kurian EM (1999) Propellants Explos Pyrotech 24:260–265

    Article  CAS  Google Scholar 

  13. Schmidt PW (1991) J Appl Cryst 24:414–435

    Article  CAS  Google Scholar 

  14. Debye P, Anderson HR Jr, Brumberger H (1957) J Appl Phys 28:679–683

    Article  ADS  CAS  Google Scholar 

  15. Hudson SD, Hutter JL, Nieh MP, Pencer J, Million LE, Wan W (2009) J Chem Phys 130:34903

    Article  CAS  Google Scholar 

  16. Schmidt PW, Anvir D, Levy D, Hohr A, Steiner M, Röll A (1991) J Chem Phys 94(2):1474–1479

    Article  ADS  CAS  Google Scholar 

Download references

Acknowledgments

Authors are thankful to Ratanesh Kumar, I. K. Singh, Sonu Gavit and Sandip Virnak from APD, BARC, for experimental assistance. Authors are thankful to Dr. V. S. Kamble, Chemistry Division, BARC, for providing facility of FTIR characterization, for characterization on xerogel samples.

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Authors and Affiliations

  1. Applied Physics Division, Bhabha Atomic Research Centre, Mumbai, 400085, India

    S. V. Ingale, P. B. Wagh & Satish C. Gupta

  2. Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai, 400085, India

    P. U. Sastry & A. K. Patra

  3. Materials Science Division, Bhabha Atomic Research Centre, Mumbai, 400085, India

    R. Tewari

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  1. S. V. Ingale
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  2. P. U. Sastry
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  3. A. K. Patra
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  4. R. Tewari
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  5. P. B. Wagh
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  6. Satish C. Gupta
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Correspondence to S. V. Ingale.

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Ingale, S.V., Sastry, P.U., Patra, A.K. et al. Micro structural investigations on TNT and PETN incorporated silica xerogels. J Sol-Gel Sci Technol 54, 238–242 (2010). https://doi.org/10.1007/s10971-010-2188-7

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  • DOI: https://doi.org/10.1007/s10971-010-2188-7

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