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Analytical application of poly[dibenzo-18-crown-6] for column chromatographic separation of Nd(III) from Ce(III), U(VI) and other elements

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Abstract

This research is dedicated to the study of analytical application of poly[dibenzo-18-crown-6] for separation of Nd(III) from possible lanthanides, actinides and other metal ions. A simple and efficient column chromatographic method has been developed using poly [dibenzo-18-crown-6] as stationary phase and hippuric acid as a counter ion. The capacity of crown polymer for Nd(III) was found to be 0.55 ± 0.01 mmol/g. Nd(III) was quantitatively separated from Ce(III), U(VI) and other elements in binary as well as multicomponent mixtures. Separation yields were good and reproducible (±2 %). This method has important application for separation of Nd(III) from Ce(III) rapidly and selectively.

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Authors and Affiliations

  1. Analytical and Environmental Research Lab, Department of Chemistry, Shivaji University, Kolhapur, 416004, Maharashtra, India

    S. N. Lad & B. S. Mohite

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  1. S. N. Lad
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  2. B. S. Mohite
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Correspondence to S. N. Lad.

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Lad, S.N., Mohite, B.S. Analytical application of poly[dibenzo-18-crown-6] for column chromatographic separation of Nd(III) from Ce(III), U(VI) and other elements. J Radioanal Nucl Chem 302, 1481–1487 (2014). https://doi.org/10.1007/s10967-014-3663-3

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  • DOI: https://doi.org/10.1007/s10967-014-3663-3

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