Abstract
A new azobenzene chromophore (AZQU), appended with a bis-quinoline unit as a turn-on chemosensor for selective detection of Cd2+ ions, has been designed and synthesized. The fluorescent receptor AZQU has an excellent selectivity and sensitivity towards Cd2+ ions over other metal ions in CH3CN:H2O (80:20, v/v) solution. AZQU is red colored and non-fluorescent in the absence of Cd2+ ions, but upon addition of Cd2+ ions it turns colorless with appreciable fluorescence. This “off–on” type signaling behavior is attributed to the CHEF (chelation-enhanced fluorescence) effect of the quinoline unit and the change in color from red to yellow occurs by an ICT process with Cd2+. The association constant for AZQU + Cd2+ was calculated to be 1.68 × 105 L·mol−1 with binding in the 1:1 stoichiometric ratio.
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Resendiz, M.J., Noveron, J.C., Disteldorf, H., Fischer, S., Stang, P.J.: A self-assembled supramolecular optical sensor for Ni(II), Cd(II), and Cr(III). Org. Lett. 6, 651–653 (2004)
Mancin, F., Rampazzo, E., Tecilla, P., Tonellato, U.: Self-assembled fluorescent chemosensors. Chem. A Eur. J. 12, 1844–1854 (2006)
Jeong, Y., Yoon, J.: Recent progress on fluorescent chemosensors for metal ions. Inorg. Chim. Acta 381, 2–14 (2012)
Lee, H.G., Lee, J.H., Jang, S.P., Hwang, I.H., Kim, S.J., Kim, Y., Harrison, R.G.: Zinc selective chemosensors based on the flexible dipicolylamine and quinoline. Inorg. Chim. Acta 394, 542–551 (2013)
Cao, S., Li, H., Chen, T., Chen, J.: A polyaza macrocycle ligand bearing anthracenyl fluorophores for selective signaling of Zn(II) in aqueous solution. J. Solution Chem. 38, 1520–1527 (2009)
Tian, M., Ihmels, H.: Selective ratiometric detection of mercury(II) ions in water with an acridizinium-based fluorescent probe. Chem. Commun. 22, 3175–3177 (2009)
Georgopoulos, A.G., Roy, M.J., Yonone-Lioy, R.E., Opiekun, P.J., Lioy, P.: Environmental copper: its dynamics and human exposure issues. J. Toxicol. Environ. Health Part B Crit. Rev. 4, 341–394 (2001)
Robards, K., Worsfold, P.: Cadmium: toxicology and analysis. A Rev. Anal. 116, 549–568 (1991)
Kim, H.N., Ren, W.X., Kim, J.S., Yoon, J.: Fluorescent and colorimetric sensors for detection of lead, cadmium, and mercury ions. Chem. Soc. Rev. 41, 3210–3244 (2012)
Peng, X., Du, J., Fan, J., Wang, J., Wu, Y., Zhao, J., Xu, T.: A selective fluorescent sensor for imaging Cd2+ in living cells. J. Am. Chem. S. 129, 1500–1501 (2007)
De Silva, A.P., Gunaratne, H.N., Gunnlaugsson, T., Huxley, A.J., McCoy, C.P., Rademacher, J.T., Rice, T.E.: Signaling recognition events with fluorescent sensors and switches. Chem. Rev. 97, 1515–1566 (1997)
Gunnlaugsson, T., Leonard, J.P.: H+, Na+ and K+ modulated lanthanide luminescent switching of Tb(III) based cyclen aromatic diaza-crown ether conjugates in water. Chem. Commun. 19, 2424–2425 (2003)
Manjunath, R., Hrishikesan, E., Kannan, P.: A selective colorimetric and fluorescent sensor for Al3+ ion and its application to cellular imaging. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 140, 509–515 (2015)
Cheng, C.C., Chen, Z.S., Wu, C.Y., Lin, C.C., Yang, C.R., Yen, Y.P.: Azo dyes featuring a pyrene unit: new selective chromogenic and fluorogenic chemodosimeters for Hg(II). Sens. Actuators B Chem. 142, 280–287 (2009)
Das, P., Ghosh, A., Das, A.: Unusual specificity of a receptor for Nd3+ among other lanthanide ions for selective colorimetric recognition. Inorg. Chem. 49, 6909–6916 (2010)
Park, H.M., Oh, B.N., Kim, J.H., Qiong, W., Hwang, I.H., Jung, K.D., Kim, J.: Fluorescent chemosensor based-on naphthol–quinoline for selective detection of aluminum ions. Tetrahedron Lett. 52, 5581–5584 (2011)
Xue, L., Liu, Q., Jiang, H.: Ratiometric Zn2+ fluorescent sensor and new approach for sensing Cd2+ by ratiometric displacement. Org. Lett. 11, 3454–3457 (2009)
Liu, Y., Zhang, N., Chen, Y., Wang, L.H.: Fluorescence sensing and binding behavior of aminobenzenesulfonamidoquinolino–β-cyclodextrin to Zn2+. Org. Lett. 9, 315–318 (2007)
Hao, E., Meng, T., Zhang, M., Pang, W., Zhou, Y., Jiao, L.: Solvent dependent fluorescent properties of a 1,2,3-triazole linked 8-hydroxyquinoline chemosensor: tunable detection from zinc(II) to iron(III) in the CH3CN/H2O system. J. Phys. Chem. A 115, 8234–8241 (2011)
Hrishikesan, E., Saravanan, C., Kannan, P.: Bis-triazole-appended azobenzene chromophore for selective sensing of copper(II) ion. Ind. Eng. Chem. Res. 50, 8225–8229 (2011)
Hrishikesan, E., Kannan, P.: Azobenzene chemosensor based on nitrogen chelator for the detection of Cu(II) ion in aqueous medium. Inorg. Chem. Commun. 37, 21–25 (2013)
Perrin, D.D., Armarego, W.L.F., Perrin, D.R.: Purification of Laboratory Chemicals, 3rd edn. Pergamon Press, New York (1988)
Gunnlaugsson, T., Leonard, J.P., Murray, N.S.: Highly selective colorimetric naked-eye Cu(II) detection using an azobenzene chemosensor. Org. Lett. 6, 1557–1560 (2004)
Huang, J., Xu, Y., Qian, X.: A colorimetric sensor for Cu2+ in aqueous solution based on metal ion-induced deprotonation: deprotonation/protonation mediated by Cu2+–ligand interactions. J. Chem. Soc. Dalton Trans. 10, 1761–1766 (2009)
Hirose, K.: A practical guide for the determination of binding constants. J. Incl. Phenom. Macrocycl. Chem. 39, 193–209 (2001)
Benesi, H.A., Hildebrand, J.H.: A spectrophotometric investigation of the interaction of iodine with aromatic hydrocarbons. J. Am. Chem. Soc. 71, 2703–2707 (1949)
Tian, D., Yan, H., Li, H.: A selective fluorescent probe of Hg2+ based on triazole-linked 8-oxyquinoline calix [4] arene by click chemistry. Supramol. Chem. 22, 249–255 (2010)
Liu, J., Wu, K., Li, X., Han, Y., Xia, M.: A water soluble fluorescent sensor for the reversible detection of tin(IV) ion and phosphate anion. RSC Adv. 3, 8924–8928 (2013)
Acknowledgments
The author E.H thanks thank the Department of Science and Technology (DST), India for financial support (DST-SR/S1/PC-07/2010). The authors P.K and R.M are thankful to the Anna Centenary Research Fellowship (ACRF), Anna University, Chennai (CR/ACRF/2013/38). The instrumentation facility was provided to our department through DST-FIST and UGC-DRS from New Delhi.
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10953_2016_473_MOESM1_ESM.doc
Characterization data of synthesized compounds and additional spectroscopic data of the receptor AZQU are available as electronic supplementary data. (DOC 2283 kb)
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Hrishikesan, E., Manjunath, R. & Kannan, P. A Bis-Quinoline Appended Azobenzene Based Naked Eye Sensor for Selective Detection of Cd2+ Ion. J Solution Chem 45, 907–919 (2016). https://doi.org/10.1007/s10953-016-0473-y
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DOI: https://doi.org/10.1007/s10953-016-0473-y