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Transfer Properties of Diglycine from Water to Aqueous Alkali Metal Nitrate Solutions

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Abstract

Enthalpies of solution and densities of diglycine in aqueous solutions of LiNO3, NaNO3 and KNO3 were measured at 298.15 K. Transfer enthalpies (\( \Delta_{\text{tr}} H \)) and transfer partial molar volumes (\( \Delta_{\text{tr}} V_{\phi }^{0} \)) were derived for diglycine. The transfer enthalpies of diglycine from water to the three alkali metal nitrates solutions are negative while the transfer partial molar volume values are positive. The absolute values of \( \Delta_{\text{tr}} H \) and \( \Delta_{\text{tr}} V_{\phi }^{0} \) from water to the same concentration in salt solutions in both cases vary in the relative order LiNO3 < KNO3 < NaNO3. The results are discussed in terms of electrostatic interaction and structural interactions. Electrostatic interaction between the diglycine zwitterion and salts gives large contributions to Δtr H and \( \Delta_{\text{tr}} V_{\phi }^{0} \). But, structursal interaction is responsible for the abnormal behavior of diglycine in aqueous LiNO3 solutions.

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References

  1. Martins, M.A.R., Ferreira, O., Hnědkovský, L., Cibulka, I., Pinho, S.P.: Partial molar volumes of glycine and DL-alanine in aqueous ammonium sulfate solutions at 278.15, 288.15, 298.15 and 308.15 K. J. Solution Chem. 43, 972–988 (2014)

    Article  CAS  Google Scholar 

  2. Liu, C.L., Zhou, L., Ma, L., Lin, R.S.: Volumetric properties of l-alanine and l-serine in aqueous N, N-dimethylformamide solutions at 298.15 K. J. Solution Chem. 42, 1572–1579 (2013)

    Article  CAS  Google Scholar 

  3. Jiang, X.F., Zhu, C.Y., Ma, Y.G.: Volumetric and viscometric studies of amino acids in L-ascorbic acid aqueous solutions at T = (293.15 to 323.15) K. J. Chem. Thermodyn. 71, 50–63 (2014)

    Article  CAS  Google Scholar 

  4. Nain, A.K., Sharma, R.: Densities and volumetric properties of binary mixtures of N, N-dimethylformamide/N, N-dimethylacetamide with some alkyl acrylates at temperatures from 288.15 K to 318.15 K. J. Chem. Thermodyn. 58, 36–45 (2013)

    Article  CAS  Google Scholar 

  5. Hernández-Mendoza, M., Zúñiga-Moreno, A., Manríquez-Ramírez, M.E., Elizalde-Solis, O.: Densities and excess molar volumes of binary systems N, N-dimethylformamide + ethanolamine or N,N-diethylethanolamine. J. Solution Chem. 43, 1981–1996 (2014)

    Article  Google Scholar 

  6. Kumar, H., Singla, M., Jindal, R.: Solvation behavior of dipeptides of alanine in aqueous solutions of antibacterial drug ampicillin at different temperatures. Thermochim. Acta 571, 28–41 (2013)

    Article  CAS  Google Scholar 

  7. Yan, Z.N., Geng, R., Gu, B.X., Pan, Q., Wang, J.J.: Densities, electrical conductances, and spectroscopic properties of glycyl dipeptide + ionic liquid ([C12mim]Br) + water mixtures at different temperatures. Fluid Phase Equilib. 367, 125–134 (2014)

    Article  CAS  Google Scholar 

  8. Choudhary, S., Kishore, N.: Interactions of some short peptides with the osmolyte trimethylamine N-oxide in aqueous solution: physico-chemical insights. J. Chem. Thermodyn. 52, 36–42 (2012)

    Article  CAS  Google Scholar 

  9. Smirnov, V.I., Badelin, V.G.: Enthalpies of solution of β-alanyl-β-alanine in aqueous solution of amides at 298.15 K. Thermochim. Acta 536, 74–76 (2012)

    Article  CAS  Google Scholar 

  10. EI-Dossoki, F.I.: Volumetric and solvation properties of glycyl-glycine and glycyl-l-leucine in aqueous acetate solutions. J. Solution Chem. 44, 264–279 (2015)

    Article  Google Scholar 

  11. Afrin, R.S.: Effect of NaCl and NaNO3 on the partial molar volumes and partial molar isentropic compressibilities of some amino acids at several different temperatures (298.15–328.15) K. J. Solution Chem. 41, 1144–1155 (2012)

    Article  Google Scholar 

  12. Lin, G.M., Bian, P.F., Lin, R.S.: The limiting partial molar volume and transfer partial molar volume of glycylglycine in aqueous sodium halide solutions at 298.15 K and 308.15 K. J. Chem. Thermodyn. 38, 144–151 (2006)

    Article  CAS  Google Scholar 

  13. Badarayani, R., Satpute, D.B., Kumar, A.: Effect of NaBr, KCl, KBr, and MgCl2 on viscosities of aqueous glycine and l-alanine solutions at 298.15 K. J. Chem. Eng. Data 50, 1083–1086 (2005)

    Article  CAS  Google Scholar 

  14. Lark, B.S., Patyar, P., Banipal, T.S., Kishore, N.: Densities, partial molar volumes, and heat capacities of glycine, l-alanine, and l-leucine in aqueous magnesium chloride solutions at different temperatures. J. Chem. Eng. Data 49, 553–565 (2004)

    Article  CAS  Google Scholar 

  15. Ramasami, P., Kakkar, R.: Partial molar volumes and adiabatic compressibilities at infinite dilution of amino carboxylicacids and glycylglycine in water and aqueous solutions of sodium sulphate at (288.15, 298.15 and 308.15) K. J. Chem. Thermodyn. 38, 1385–1395 (2006)

    Article  CAS  Google Scholar 

  16. Liu, C.L., Lin, R.S., Xu, N.: Enthalpies of transfer of amino acids from water to aqueous solutions of alkali metal nitrates. J. Chem. Eng. Data 50, 2094–2096 (2005)

    Article  CAS  Google Scholar 

  17. Wang, X., Guo, Y.H., Zheng, Q., Lin, R.S.: Transfer enthalpies of amino acids and glycine peptides from water to aqueous solutions of trimethylamine N-oxide at 298.15 K. Thermochim. Acta 587, 48–51 (2014)

    Article  CAS  Google Scholar 

  18. Nowicka, B., Piekarski, H.: Calorimetric studies of interactions between simple peptides and electrolytes in water at 298.15 K. J. Mol. Liq. 95, 323–328 (2009)

    Article  Google Scholar 

  19. Davis, K.G., Gallardo-Jiménez, M.A., Lilley, T.H.: Aqueous solutions containing amino acids and peptides-26. The enthalpies of interaction of some glycyl and alanyl peptides with sodium chloride and potassium chloride in water at 25 °C. Fluid Phase Equilib. 57, 191–204 (1990)

    Article  CAS  Google Scholar 

  20. Lilley, T.H., Moses, E., Tasker, I.R.: Aqueous solutions containing amino acids and peptides. Part 10. Enthalpy of interaction of glycine with some alkali metal chlorides at 298.15 K. J. Chem. Soc. Faraday Trans. I 76, 906–914 (1980)

    Article  CAS  Google Scholar 

  21. Visser, C.D., Perron, G., Desnoyers, J.E.: Volumes and heat capacities of ternary aqueous systems at 25º. Mixtures of urea, tert-butyl alcohol, dimethylformamide and water. J. Am. Chem. Soc. 99, 5894–5900 (1977)

    Article  Google Scholar 

  22. Desnoyers, J.E., Arel, M., Perron, G., Jolicoeur, C.: Apparent molal volumes of alkali halides in water at 25º. Influence of structural hydration interactions on the concentration dependence. J. Phys. Chem. 73, 3346–3351 (1969)

    Article  CAS  Google Scholar 

  23. Hedwing, G.R., Reading, J.F., Lilley, T.H.: Aqueous solutions containing amino acids and peptides: part 27. Partial molar heat capacities and partial molar volumes of some N-acetyl amino acid amides, some N-acetyl peptide amides and two peptides at 25 °C. J. Chem. Soc. Faraday Trans. 87, 1751–1758 (1991)

    Article  Google Scholar 

  24. Mishra, A.K., Ahluwalia, J.C.: Apparent molal volumes of amino acids, N-acetylamino acids, and peptides in aqueous solutions. J. Phys. Chem. 88, 86–92 (1984)

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the Science-Technology Foundation for Middle-Aged and Young Scientists of Shandong Province (BS2011SF026).

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Authors and Affiliations

  1. Department of Chemistry and Chemistry Engineering, Zaozhuang University, Zaozhuang, 277160, People’s Republic of China

    Li Zhou, Chunli Liu, Liqun Fan, Jinhu Wang & Shumin Wang

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  1. Li Zhou
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  2. Chunli Liu
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  3. Liqun Fan
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  4. Jinhu Wang
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  5. Shumin Wang
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Correspondence to Chunli Liu.

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Zhou, L., Liu, C., Fan, L. et al. Transfer Properties of Diglycine from Water to Aqueous Alkali Metal Nitrate Solutions. J Solution Chem 44, 2383–2392 (2015). https://doi.org/10.1007/s10953-015-0416-z

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  • DOI: https://doi.org/10.1007/s10953-015-0416-z

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