Skip to main content
Log in

Effect of Film Thickness in Electrical Resistivity and Magnetic Properties of Nd0.7Sr0.3MnO3 Thin Films

  • Original Paper
  • Published:
Journal of Superconductivity and Novel Magnetism Aims and scope Submit manuscript

Abstract

Nd0.7Sr0.3MnO3 thin films of different thicknesses were deposited on (001)-MgO substrate by using a radio frequency-magnetron sputtering system. These films were divided into two batches and were post-annealed separately in an air and oxygen environment, respectively, at 700 °C. Analysis of X-ray diffraction patterns shows that these films crystallise in cubic structure with a typical lattice constant a = 3.847 Ȧ and it expands with increase in film thickness. Both air- and oxygen-annealed films exhibit ferromagnetic transition and the transition temperature gradually rises as the film thickness is increased. Magnetisation loops recorded at 50 K show that all the prepared thin films show ferromagnetic behaviour with a maximum saturation magnetisation value (3.6 μ B ) comparable to that of bulk sample. The anisotropy constant (K) estimated from the analysis of initial magnetisation curve is found to decrease with increase in film thickness. Metal-insulator transition has been observed and the resistivity data in the insulating region were analysed based on variable range hopping model.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Kawashima, K., Logvenov, G., Christiani, G., Habermeier, H.U.: Interrelation of epitaxial strain and oxygen deficiency in La0.7Ca0.3MnO3−δ thin films. J. Magn. Magn. Mater. 378, 539–545 (2015)

  2. Salvato, M., Vecchione, A., De Santis, A., Bobba, F., Cucolo, A.M.: Metal-insulator transition temperature enhancement in La0.7Ca0.3MnO3 thin films. J. Appl. Phys. 97(10), 103712 (2005)

    Article  ADS  Google Scholar 

  3. Sirena, M., Haberkorn, N., Granada, M., Steren, L.B., Guimpel, J.: Metal-insulator transition induced by postdeposition annealing in low doped manganite films. J. Appl. Phys. 105(3), 033902 (2009)

    Article  ADS  Google Scholar 

  4. Campillo, G., Berger, A., Osorio, J., Pearson, J.E., Bader, S.D., Baca, E., Prieto, P.: Substrate dependence of magnetic properties of La0.67Ca0.33MnO3 films. J. Magn. Magn. Mater. 237(1), 61–68 (2001)

    Article  ADS  Google Scholar 

  5. Steren, L.B., Sirena, M., Guimpel, J.: Substrate influence on the magnetoresistance and magnetic order in La0.6Sr0.4MnO3 films. J. Magn. Magn. Mater. 211(1–3), 28–34 (2000)

    Article  ADS  Google Scholar 

  6. Vengalis, B., Maneikis, A., Anisimovas, F., Butkut, R., Dapkus, L., Kindurys, A.: Effect of strains on electrical and optical properties of thin La 0.67Ca0.33MnO3 films. J. Magn. Magn. Mater. 211(1–3), 35–40 (2000)

    Article  ADS  Google Scholar 

  7. Shaowei, J., Guanyin, G., Wenbin, W., Xianyi, Z.: Effect of angular-distortion-induced strain on structural and transport properties of epitaxial La 0.7Sr0.3MnO 3 thin films. J. Phys. D Appl. Phys. 40(2), 305 (2007)

    Article  Google Scholar 

  8. Zhizhen, Y., Guanyin, G., Zhen, H., Xingli, J., Qinzhuang, L., Wenbin, W.: Oxygen in-diffusion at room temperature in epitaxial La 0.7 Ca 0.3 MnO 3−δ thin films. J. Phys. D. Appl. Phys. 42(12), 125002 (2009)

    Article  Google Scholar 

  9. Song, X.F., Lian, G.J., Xiong, G.C.: Small polaronic transport in oxygen-deficient La0.7Ca0.3MnO3−δ thin films. Physical Review B 71(21), 214427 (2005)

  10. Sakai, J., Ito, N., Imai, S.: Oxygen content of La1–xSrxMnO3–y thin films and its relation to electric-magnetic properties. J. Appl. Phys. 99(8), 08Q318 (2006)

    Article  Google Scholar 

  11. Li, T., Wang, B., Dai, H., Du, Y., Yan, H., Liu, Y.: Annealing effect on the structural and magnetic properties of La0.7Sr0.3MnO3 films. J. Appl. Phys. 98(12), 123505 (2005)

    Article  ADS  Google Scholar 

  12. Dho, J., Hur, N.H., Kim, I.S., Park, Y.K.: Oxygen pressure and thickness dependent lattice strain in La0.7Sr0.3MnO3 films. J. Appl. Phys. 94(12), 7670–7674 (2003)

    Article  ADS  Google Scholar 

  13. Petrisor, T., Gabor, M.S., Boulle, A., Bellouard, C., Tiusan, C., Pana, O., Petrisor, T.: Oxygen incorporation effects in annealed epitaxial La(1–x)SrxMnO3 thin films. J. Appl. Phys. 109(12), 123913 (2011)

    Article  ADS  Google Scholar 

  14. Barman, A., Koren, G.: Thickness-dependent transport properties of Nd2/3Sr1/3MnO3 thin films. Appl. Phys. Lett. 77(11), 1674–1676 (2000)

    Article  ADS  Google Scholar 

  15. Jin, S.W., Gao, G.Y., Yin, Z.Z., Huang, Z., Zhou, X.Y., Wu, W.B.: Strain state evolution and thickness-dependent properties of epitaxial Nd0.7Sr0.3MnO3 films. Phys. Rev. B 75(21), 212401 (2007)

    Article  ADS  Google Scholar 

  16. Meng, Y., He, W., Li, A., Li, G., Jin, S.: Effects of oxygen content on the structural and transport properties in epitaxial thin films. Phys. B 407(13), 2416–2420 (2012)

    Article  ADS  Google Scholar 

  17. Xiong, G.C., Li, Q., Ju, H.L., Greene, R.L., Venkatesan, T.: Influence of preparation on resistivity behavior of epitaxial Nd0.7Sr0.3MnO3−δ and La0.67Ba0.33MnO3−δ thin films. Appl. Phys. Lett. 66(13), 1689–1691 (1995)

  18. Wang, H., Zhang, X., Hundley, M.F., Thompson, J.D., Gibbons, B.J., Lin, Y., Arendt, P.N., Foltyn, S.R., Jia, Q.X., MacManus-Driscoll, J.L.: Effect of crystallinity on the transport properties of Nd0.67Sr0.33MnO3 thin films. Appl. Phys. Lett. 84(7), 1147–1149 (2004)

    Article  ADS  Google Scholar 

  19. Phan, T.L., Khiem, N.V., Phuc, N.X., Yu, S.C.: Electrical and magnetic behaviors in Nd0.7Sr0.3MnO3 with different annealing periods. J. Magn. Magn. Mater. 304(1), e334–e336 (2006)

    Article  ADS  Google Scholar 

  20. Sun, Z.H., Dai, S., Zhou, Y.L., Cao, L.Z., Chen, Z.H.: Elaboration and optical properties of GaFeO3 thin films. Thin Solid Films 516(21), 7433–7436 (2008)

    Article  ADS  Google Scholar 

  21. Xiong, Y.M., Chen, T., Wang, G.Y., Chen, X.H., Chen, X., Chen, C.L.: Raman spectra in epitaxial thin films of La1-xCaxMnO3 (x = 0.33, 0.5) grown on different substrates. Phys. Rev. B 70(9), 094407 (2004)

    Article  ADS  Google Scholar 

  22. Iliev, M.N., Abrashev, M.V., Lee, H.G., Popov, V.N., Sun, Y.Y., Thomsen, C., Meng, R.L., Chu, C.W.: Raman spectroscopy of orthorhombic perovskitelike YMnO3 and LaMnO3. Phys. Rev. B 57(5), 2872–2877 (1998)

    Article  ADS  Google Scholar 

  23. Balasubramanian, B., Skomski, R., Li, X., Valloppilly, S.R., Shield, J.E., Hadjipanayis, G.C., Sellmyer, D.J.: Cluster Synthesis and Direct Ordering of Rare-Earth Transition-Metal Nanomagnets. Nano Lett. 11(4), 1747–1752 (2011)

    Article  ADS  Google Scholar 

  24. Hadjipanayis, G., Sellmyer, D.J., Brandt, B.: Rare-earth-rich metallic glasses. I. Magnetic hysteresis. Phys. Rev. B 23(7), 3349–3354 (1981)

    Article  ADS  Google Scholar 

  25. Xiong, C.M., Sun, J.R., Shen, B.G.: Dependence of magnetic anisotropy of the La0.67Ca0.33MnO3 films on substrate and film thickness. Solid State Commun. 134(7), 465–469 (2005)

    Article  ADS  Google Scholar 

  26. Paul, D.K., Mitra, S.S.: Evaluation of Mott’s Parameters for Hopping Conduction in Amorphous Ge, Si, and Se-Si. Phys. Rev. Lett. 31(16), 1000–1003 (1973)

    Article  ADS  Google Scholar 

Download references

Acknowledgments

Authors are thankful to CSIR, New Delhi [03(1253)/12/EMR-II], and UGC-DAE-CSR, Mumbai [UDCSR/MUM/CD/CRSM-192], for financial support. CIF, IIT Guwahati is acknowledged for Raman spectroscopy facility.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. Ravi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gopalarao, T.R., Ravi, S. & Pamu, D. Effect of Film Thickness in Electrical Resistivity and Magnetic Properties of Nd0.7Sr0.3MnO3 Thin Films. J Supercond Nov Magn 29, 2567–2572 (2016). https://doi.org/10.1007/s10948-016-3563-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10948-016-3563-6

Keywords

Navigation