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Selective functionalization of external and internal surface of MCM-41 for adsorptive desulfurization

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Abstract

MCM-41 was selectively functionalized with CuO on the external surface and Cu2+ coordinated by organosilanes on the internal surface. The production of CuO and removal of template were achieved in one step, which is convenient and a save of energy. Results of transmission electron microscopy indicate the presence of CuO on outer surface of MCM-41. The successful grafting of organosilanes was confirmed by 13C and 29Si nuclear magnetic resonance. The prepared M(CuO)N(Cu) shows more comprehensive desulfurization performance due to the simultaneous and independent incorporation of CuO and copper ions. Dimethyl sulfide and dimethyl disulfide are selectively adsorbed on external surface of M(CuO)N(Cu), while tert-butyl mercaptan can be adsorbed on both external and internal surface of M(CuO)N(Cu).

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Acknowledgments

The authors thank the National Natural Science Foundation of China (Grant 21376265) for financial support.

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Authors and Affiliations

  1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, 266580, People’s Republic of China

    Lechun Song, Zunbin Duan, Lijun Zhu, Yulu Zhou, Yuzhi Xiang & Daohong Xia

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  1. Lechun Song
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  2. Zunbin Duan
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  3. Lijun Zhu
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  4. Yulu Zhou
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Correspondence to Daohong Xia.

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The authors declare no potential conflicts of interest, no research involving Human Participants and/or Animals. The work described has been approved by all co-authors and the responsible authorities at the institute(s).

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Song, L., Duan, Z., Zhu, L. et al. Selective functionalization of external and internal surface of MCM-41 for adsorptive desulfurization. J Porous Mater 23, 1181–1187 (2016). https://doi.org/10.1007/s10934-016-0176-1

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