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Low cost rapid route for hydrothermal synthesis of nano ZSM-5 with mixture of two, three and four structure directing agents

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Abstract

This article aims at investigating the effect of different structure directing agents such as TPAOH, TPABr, EDA and ethanol solely or as dual, triple or quad mixture on the synthesis and characteristics of nano ZSM-5 zeolite such as crystallinity and crystal size, and also its catalytic properties in MTG process. It is found out that application of a quad mixture of different structure directing agents not also reduces the synthesis cost compares to samples synthesized with one template but also ZSM-5 with small particle size, high crystallinity and improved catalytic properties will be obtained in a short crystallization period.

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References

  1. T.F. Wang, J.F. Wang, Y. Jin, Ind. Eng. Chem. Res. 46, 242 (2007)

    Article  Google Scholar 

  2. H.A. Zaidi, K.K. Pant, Catal. Today 96, 243 (2004)

    Article  Google Scholar 

  3. A. Corma, Chem. Rev. 97, 2373 (1997)

    Article  CAS  Google Scholar 

  4. M.E. Davis, Nature 41, 813 (2002)

    Article  Google Scholar 

  5. C.S. Cundy, P.A. Cox, Chem. Rev. 103, 663 (2003)

    Article  CAS  Google Scholar 

  6. M.A. den Hollander, M. Wissink, M. Makkee, J.A. Moulijn, Appl. Catal. A 223, 85 (2002)

    Article  Google Scholar 

  7. J. Perez-Ramirez, F. Kapteijn, J.C. Groen, A. Domenech, G. Mul, J.A. Moulijn, J. Catal. 214, 33 (2003)

    Article  CAS  Google Scholar 

  8. H. Feng, C. Li, H. Shan, Appl. Clay Sci. 42, 439 (2009)

    Article  CAS  Google Scholar 

  9. S. van Donk, A. Broersma, O.L.J. Gijzeman, J.A. van Bokhoven, J.H. Bitter, K.P. de Jong, J. Catal. 204, 272 (2001)

    Article  Google Scholar 

  10. S. Miar Alipour, R. Halladj, S. Askari, Rev. Chem. Eng. 30, 289 (2014)

    Google Scholar 

  11. F. Mohammadparast, R. Halladj, S. Askari, Chem. Eng. Commun. 202, 542 (2015)

    Article  CAS  Google Scholar 

  12. F. Rezaei, P. Webley, Sep. Purif. Technol. 70, 243 (2010)

    Article  CAS  Google Scholar 

  13. Y.S. Tao, H. Kanoh, K. Kaneko, J. Am. Chem. Soc. 125, 6044 (2003)

    Article  CAS  Google Scholar 

  14. A. Petushkov, S. Yoon, S.C. Larsen, Micropor. Mesopor. Mater. 137, 92 (2011)

    Article  CAS  Google Scholar 

  15. R.M. Mohamed, H.M. Aly, M.F. El-Shahat, I.A. Ibrahim, Micropor. Mesopor. Mater. 79, 7 (2005)

    Article  CAS  Google Scholar 

  16. H. Kalipcilar, A. Culfaz, Cryst. Res. Technol. 36, 1197 (2001)

    Article  CAS  Google Scholar 

  17. S. Askari, R. Halladj, M. Sohrabi, Rev. Adv. Mater. Sci. 32, 83 (2012)

    CAS  Google Scholar 

  18. L. Shirazi, E. Jamshidi, M.R. Ghasemi, Cryst. Res. Technol. 43, 1300 (2008)

    Article  CAS  Google Scholar 

  19. W.J. Kim, M.C. Lee, D.T. Hayhurst, Micropor. Mesopor. Mater. 26, 133 (1998)

    Article  CAS  Google Scholar 

  20. S. Sang, F. Chang, Z. Liu, C. He, Y. He, L. Xu, Catal. Today 93, 729 (2004)

    Article  Google Scholar 

  21. M.K. Jung, M.H. Kim, S.S. Hong, Micropor. Mesopor. Mater. 26, 153 (1998)

    Article  CAS  Google Scholar 

  22. P. Phiriyawirut, R. Magaraphan, A.M. Jamieson, S. Wongkasemjit, Mater. Sci. Eng., A 361, 147 (2003)

    Article  Google Scholar 

  23. S.G. Thoma, T.M. Nenoff, Micropor. Mesopor. Mater. 41, 295 (2000)

    Article  CAS  Google Scholar 

  24. N. Kumar, V. Nieminen, K. Demirkan, T. Salmi, D.Y. Murzin, E. Laine, App. Cat. A: General 235, 113 (2002)

    Article  CAS  Google Scholar 

  25. S. Askari, Z. Sedighi, R. Halladj, Micropor. Mesopor. Mater. 197, 229 (2014)

    Article  CAS  Google Scholar 

  26. R. Anuwattana, K.J. Balkus Jr., S. Asavapisit, P. Khummongkol, Micropor. Mesopor. Mater 111, 260 (2008)

    Article  CAS  Google Scholar 

  27. N. Kumar, O.V. Masloboischikova, L.M. Kustov, T. Heikkila, T. Salmi, D.Y. Murzin, Ultrason. Sonochem. 14, 122 (2007)

    Article  CAS  Google Scholar 

  28. Y. Liu, W. Huang, Y. Zhao, T. Dou, React. Kinet. Catal. Lett. 96, 157 (2009)

    Article  CAS  Google Scholar 

  29. S. Askari, S. MiarAlipour, R. Halladj, M.D. Farahani, J. Porous Mater. 20, 285 (2013)

    Article  CAS  Google Scholar 

  30. F. Marzpour Shalmani, R. Halladj, S. Askari, Powder Technol. 221, 395 (2012)

  31. S. Askari, R. Halladj, Ultrason. Sonochem. 19, 554 (2012)

    Article  CAS  Google Scholar 

  32. S. Askari, R. Halladj, J. Solid State Chem. 201, 85 (2013)

    Article  CAS  Google Scholar 

  33. R.M. Mohamed, O.A. Fouad, A.A. Ismail, I.A. Ibrahim, Mater. Lett. 59, 3441 (2005)

    Article  CAS  Google Scholar 

  34. M. Noack, M. Schneider, A. Dittmar, G. Georgi, J. Caro, Micropor. Mesopor. Mater. 117, 10 (2009)

    Article  CAS  Google Scholar 

  35. E.N. Coker, J.C. Jansen, F. DiRenzo, F. Fajula, J. Martens, P. Jacobs, A. Sacco, Micropor. Mesopor. Mater. 46, 223 (2001)

    Article  CAS  Google Scholar 

  36. O.A. Fouad, R.M. Mohamed, M.S. Hassan, I.A. Ibrahim, Catal. Today 116, 82 (2006)

    Article  CAS  Google Scholar 

  37. N.L. Chauhan, J. Das, R.V. Jasra, P.A. Parikh, Z.V.P. Murthy, Mater. Lett. 74, 115 (2012)

    Article  CAS  Google Scholar 

  38. N. Najafi, S. Askari, R. Halladj, Powder Technol. 254, 324 (2014)

    Article  CAS  Google Scholar 

  39. S. Sang, F. Chang, Z. Liu, C. He, Y. He, L. Xu, Catal. Today 93, 729 (2004)

    Article  Google Scholar 

  40. L. Xu, G. Wang, Y. Wei, Y. Qi, Petrochem. Technol. 29, 248 (2000)

    CAS  Google Scholar 

  41. A.A. Rownaghi, F. Rezaei, J. Hedlund, Catal. Comm. 14, 37 (2011)

    Article  CAS  Google Scholar 

  42. Z. Wan, C. Wang, H. Yang, D. Zhang, Chemeca Conf. (2013)

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Authors and Affiliations

  1. Faculty of Chemical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Hafez Ave., P.O. Box 15875–4413, Tehran, Iran

    Shayan Miar Alipour, Rouein Halladj & Sima Askari

  2. Faculty of Chemical Engineering, School of Chemical, Biological, and Environmental Engineering, Oregon State University, Corvallis, OR, 97331, USA

    Elham BagheriSereshki

Authors
  1. Shayan Miar Alipour
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  2. Rouein Halladj
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  3. Sima Askari
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  4. Elham BagheriSereshki
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Correspondence to Rouein Halladj.

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Miar Alipour, S., Halladj, R., Askari, S. et al. Low cost rapid route for hydrothermal synthesis of nano ZSM-5 with mixture of two, three and four structure directing agents. J Porous Mater 23, 145–155 (2016). https://doi.org/10.1007/s10934-015-0064-0

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  • DOI: https://doi.org/10.1007/s10934-015-0064-0

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