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Synthesis and characterization of Ni and Zn Schiff base complexes supported on modified MCM-41 as reusable catalysts for various oxidation reactions

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Abstract

Using post grafting method, two hybrids composite materials were prepared by anchoring Nickel and Zinc Schiff base complexes onto amino-modified MCM-41(Ni-MCM-41 and Zn-MCM-41). The prepared catalysts have been characterized by FT-IR spectroscopy, thermogravimetric analysis, and transmission electron microscopy, powder X-ray diffraction and N2 adsorption–desorption isotherms. The catalysts showed excellent catalytic efficiency in oxidation reaction of sulfides to sulfoxides and oxidative coupling of thiols to their corresponding disulfides using urea hydrogen peroxide as oxidant under mild reaction conditions. The supported Schiff base complexes can be recovered easily and reused many times without significant loss in catalytic activity and selectivity.

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References

  1. P. Chen, B. Fan, M. Song, C. Jin, J. Ma, R. Li, Catal. Commun. 7, 969 (2006)

    Article  CAS  Google Scholar 

  2. A. Mobinikhaledi, M. Zendehdel, S.M.B. Hosseini-Ghazvin, P. Safari, Transit. Metal. Chem. 40, 313 (2015)

    Article  CAS  Google Scholar 

  3. S. Bhunia, S. Koner, Polyhedron 30, 1857 (2011)

    Article  CAS  Google Scholar 

  4. J.M. Thomas, R. Raja, J. Organomet. Chem. 689, 4110 (2004)

    Article  CAS  Google Scholar 

  5. Y.C. Lee, S. Dutta, K.C.W. Wu, ChemSusChem 7, 3241 (2014)

    Article  CAS  Google Scholar 

  6. Y. Li, Q. Ma, Z. Liu, X. Wang, X. Su, Anal. Chim. Acta 840, 68 (2014)

    Article  CAS  Google Scholar 

  7. M. Ziolek, Catal. Today 90, 145 (2004)

    Article  CAS  Google Scholar 

  8. R. Wojcieszak, S. Monteverdia, M. Mercy, I. Nowak, M. Ziolek, M.M. Bettahar, Appl. Catal. A Gen. 268, 241 (2004)

    Article  CAS  Google Scholar 

  9. P. Carraro, V. Elıas, A.A. Garcıa, K. Blanco, M. Oliva, Int. J. Hydrogen Energy 39, 8749 (2014)

    Article  CAS  Google Scholar 

  10. E. Rossetto, B.P. Nicola, R.F. de Souza, K. Bernardo-Gusmao, S.B.C. Pergher, J. Catal. 323, 45 (2015)

    Article  CAS  Google Scholar 

  11. M. Silva, M.J.F. Calvete, N.P.F. Goncalves, H.D. Burrows, M. Sarakha, A. Fernandes, M.F. Ribeiro, M.E. Azenha, M.M. Pereira, J. Hazard. Mater. 233, 79 (2012)

    Article  Google Scholar 

  12. A. Ghorbani-Choghamarani, J. Zeinivand, J. Iran. Chem. Soc. 7, 190 (2010)

    Article  CAS  Google Scholar 

  13. M.C. Carreno, Chem. Rev. 95, 1717 (1995)

    Article  CAS  Google Scholar 

  14. A. Supale, G. Gokavi, React. Kinet. Catal. Lett. 93, 141 (2008)

    Article  CAS  Google Scholar 

  15. J.C. Lukesh, K.K. Wallin, R.T. Raines, Chem. Commun. 50, 9591 (2014)

    Article  CAS  Google Scholar 

  16. M. Van Der Horst, K.G. Hendrikse, C.D. Woolard, J. Appl. Polym. Sci. 89, 47 (2003)

    Article  Google Scholar 

  17. L. Bruelisauer, M.A. Gauthier, J.C. Leroux, J. Control. Release 195, 147 (2014)

    Article  Google Scholar 

  18. M. Nikoorazm, A. Ghorbani-Choghamarani, H. Mahdavi, S.M. Esmaeili, Microporous Mesoporous Mater. 211, 174 (2015)

    Article  CAS  Google Scholar 

  19. M. Nikoorazm, A. Ghorbani-Choghamarani, F. Ghorbani, H. Mahdavi, Z. Karamshahi, J. Porous. Mater. 22, 261 (2015)

    Article  CAS  Google Scholar 

  20. M. Nikoorazm, A. Ghorbani-Choghamarani, N. Noori, J. Porous. Mater. 22, 877 (2015)

    Article  CAS  Google Scholar 

  21. M.M. Lakouraj, M. Tajbakhsh, F. Shirini, M.V. Asady Tamami, Synth. Commun. 22, 261 (2005)

    Google Scholar 

  22. A. Shaabani, A. Bazgir, K. Soleimani, P. Salehi, Synth. Commun. 33, 2935 (2003)

    Article  CAS  Google Scholar 

  23. M. Abdo, Z. Yong, V.L. Schramm, S. Knapp, Org. Lett. 12, 2982 (2010)

    Article  CAS  Google Scholar 

  24. Y. Inbushi, M. Yoshihara, Phosphorus Sulfur 103, 101 (1995)

    Article  Google Scholar 

  25. F.R. Bisogno, A. Rioz-Martnez, C. Rodguez, I. Lavandera, G. de Gonzalo, D.E. Torres Pazmino, M.W. Fraaije, V. Gotor, Chem. Catal. 2, 946 (2010)

    CAS  Google Scholar 

  26. A. Ghorbani-Choghamarani, G. Azadi, B. Tahmasbi, M. Hadizadeh-Hafshejani, Z. Abdi, Phosphorus Sulfur 189, 433 (2014)

    Article  CAS  Google Scholar 

  27. A. Ghorbani-Choghamarani, H. Goudarziafshar, M. Nikoorazm, S. Yousefi, Lett. Org. Chem. 6, 335 (2009)

    Article  CAS  Google Scholar 

  28. A. Ghorbani-Choghamarani, S. Sardari, J. Sulfur Chem. 32, 63 (2011)

    Article  CAS  Google Scholar 

  29. A. Ghorbani-Choghmarani, M. Nikoorazm, H. Goudarziafshar, A. Shokr, H. Almasi, J. Chem. Sci. 123, 453 (2011)

    Article  Google Scholar 

  30. B. Karami, M. Montazerozohori, M.H. Habibi, Molecules 10, 1358 (2005)

    Article  CAS  Google Scholar 

  31. A. Rostami, B. Tahmasbi, F. Abedi, Z. Shokri, J. Mol. Catal. A: Chem. 378, 200 (2013)

    Article  CAS  Google Scholar 

  32. A. Ghorbani-Choghamarani, Z. Darvishnejad, M. Norouzi, Appl. Organometal. Chem. 29, 170 (2015)

    Article  CAS  Google Scholar 

  33. M. Mansour Lakouraj, M. Tajbakhsh, H. Tashakkorian, Monatsh. Chem. 138, 83 (2007)

    Article  Google Scholar 

  34. A.G. Mei Wang, J. Shi, D. Wang, W. Tian, L. Sun, Appl. Organometal. Chem. 20, 830 (2006)

    Article  Google Scholar 

  35. M. Lakshmi Kantam, B.V. Prakash, B. Bharathi, Ch. Venkat Reddy, J. Mol. Catal A: Chem. 226, 119 (2005)

    Article  Google Scholar 

  36. K. Masayuki, A. Yasutaka, O. Shiho, N. Takuya, H. Akihiko, H. Yoshiro, Synthesis 21, 3286 (2007)

    Google Scholar 

  37. L. Menini, M.C. Pereira, A.C. Ferreira, J.D. Fabris, E.V. Gusevskaya, Appl. Catal A: Gen. 392, 151 (2011)

    Article  CAS  Google Scholar 

  38. P.J. Chai, Y. Shu Li, C. Xia Tan, Chin. Chem. Lett. 22, 1403 (2011)

    Article  CAS  Google Scholar 

  39. H. Imanieh, S. Ghamami, M.K. Mohammadi, A. Jangjoo, Russ. J. Gen. Chem. 77, 282 (2007)

    Article  CAS  Google Scholar 

  40. A. Akdag, T. Webb, S.D. Worley, Tetrahedron Lett. 47, 3509–3510 (2006)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ilam University, P. O. Box 69315516, Ilam, Iran

    Nourolah Noori, Mohsen Nikoorazm & Arash Ghorbani-Choghamarani

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  1. Nourolah Noori
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  2. Mohsen Nikoorazm
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  3. Arash Ghorbani-Choghamarani
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Correspondence to Mohsen Nikoorazm.

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Noori, N., Nikoorazm, M. & Ghorbani-Choghamarani, A. Synthesis and characterization of Ni and Zn Schiff base complexes supported on modified MCM-41 as reusable catalysts for various oxidation reactions. J Porous Mater 22, 1607–1615 (2015). https://doi.org/10.1007/s10934-015-0044-4

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