Skip to main content
Log in

La-modified mesoporous TiO2 nanoparticles with enhanced photocatalytic activity for elimination of VOCs

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

La-modified mesoporous TiO2 were synthesized via a sol–gel route using Pluronic P123 as template. The XRD and TEM results show that La loading favors the formation of anatase with smaller crystal size. The photocatalytic activity of the mesoporous anatase was tested in photocatalytic elimination of VOCs. The photocatalysts exhibited higher activity than that of the commercial photocatalyst (Degussa, P25) under either ultraviolet or visible light irradiation. The superior activity of the mesoporous anatase may be attributed to the synergic effects of the surface area, crystal size and loaded La species.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. S. Wang, H.M. Ang, M.O. Tade, Environ. Int. 33, 694 (2007)

    Article  CAS  Google Scholar 

  2. Z. Liu, X. Zhang, S. Nishimoto, T. Murakami, A. Fujishima, Environ. Sci. Technol. 42, 8547 (2008)

    Article  CAS  Google Scholar 

  3. S. Sumitsawan, J. Cho, M.L. Sattler, R.B. Timmons, Environ. Sci. Technol. 45, 6970 (2011)

    Article  CAS  Google Scholar 

  4. T. Tabakova, D. Dimitrov, M. Manzoli, F. Vindigni, P. Petrova, L. Ilieva, R. Zanella, K. Ivanov, Catal. Commun. 35, 51 (2013)

    Article  CAS  Google Scholar 

  5. H. Li, Z. Bian, J. Zhu, D. Zhang, G. Li, Y. Huo, H. Li, Y. Lu, J. Am. Chem. Soc. 129, 8406 (2007)

    Article  CAS  Google Scholar 

  6. W. Ren, Z. Ai, F. Jia, L. Zhang, X. Fan, Z. Zou, Appl. Catal. B Environ. 69, 138 (2007)

    Article  CAS  Google Scholar 

  7. M. Zukalova, A. Zukal, L. Kavan, M.K. Nazeeruddin, P. Liska, M. Gratzel, Nano Lett. 5, 1789 (2005)

    Article  CAS  Google Scholar 

  8. G. Liu, Z. Chen, C. Dong, Y. Zhao, F. Li, G.Q. Lu, H. Cheng, J. Phys. Chem. B 110, 20823 (2006)

    Article  CAS  Google Scholar 

  9. K. Nakata, A. Fujishima, J. Photochem. Photobiol. C 13, 169 (2012)

    Article  CAS  Google Scholar 

  10. A. Kudo, H. Kato, Chem. Phys. Lett. 331, 373 (2000)

    Article  CAS  Google Scholar 

  11. L.Q. Jing, X.J. Sun, B.F. Xin, B.Q. Wang, W.M. Cai, H.G. Fu, J. Solid State Chem. 177, 3375 (2004)

    Article  CAS  Google Scholar 

  12. A.W. Xu, Y. Gao, H.Q. Liu, J. Catal. 207, 151 (2002)

    Article  CAS  Google Scholar 

  13. D.W. Hwang, J.S. Lee, W. Li, S.H. Oh, J. Phys. Chem. B 107, 4963 (2003)

    Article  CAS  Google Scholar 

  14. S. Anandan, A. Vinu, K.L.P.S. Lovely, N. Gokulakrishnan, P. Srinivasu, T. Mori, V. Murugesan, V. Sivamurugan, K. Ariga, J. Mol. Catal. A Chem. 266, 149 (2007)

    Article  CAS  Google Scholar 

  15. F.B. Li, X.Z. Li, M.F. Hou, Appl. Catal. B Environ. 48, 185 (2004)

    Article  CAS  Google Scholar 

  16. Y.N. Huo, J. Zhu, J.X. Li, G.S. Li, H.X. Li, J. Mol. Catal. A-Chem. 278, 237 (2007)

    Article  CAS  Google Scholar 

  17. K. Dai, T. Peng, H. Chen, J. Liu, L. Zan, Environ. Sci. Technol. 43, 1540 (2009)

    Article  CAS  Google Scholar 

  18. Y. Zhang, A.H. Yuwono, J. Wang, J. Li, J. Phys. Chem. C 113, 21406 (2009)

    Article  CAS  Google Scholar 

  19. L. Kumaresan, A. Prabhu, M. Palanichamy, E. Arumugam, V. Murugesan, J. Hazard. Mater. 186, 1183 (2011)

    Article  CAS  Google Scholar 

  20. J. Tang, X. Chen, Y. Liu, W. Gong, Z. Peng, T. Cai, L. Jin, Q. Deng, J. Phys. Chem. Solids 73, 198 (2012)

    Article  CAS  Google Scholar 

  21. Z. Ding, G.Q. Lu, P.F. Greenfield, J. Phys. Chem. B 104, 4815 (2000)

    Article  CAS  Google Scholar 

  22. A. Sclafani, J.M. Herrmann, J. Phys. Chem. 100, 13655 (1996)

    Article  CAS  Google Scholar 

  23. W. Hung, S. Fu, J. Tseng, H. Chu, T. Ko, Chemosphere 66, 2142 (2007)

    Article  CAS  Google Scholar 

  24. H. Choi, E. Stathatos, D.D. Dionysiou, Appl. Catal. B Environ. 63, 60 (2006)

    Article  CAS  Google Scholar 

  25. W.Y. Choi, A. Termin, M.R. Hoffmann, J. Phys. Chem. 98, 13669 (1994)

    Article  Google Scholar 

  26. T. Cai, Y. Liao, Z. Peng, Y. Long, Z. Wei, Q. Deng, J. Environ. Sci. 21, 997 (2009)

    Article  CAS  Google Scholar 

  27. A.A. Ismail, D.W. Bahnemann, L. Robben, V. Yarovyi, M. Wark, Chem. Mater. 22, 108 (2010)

    Article  CAS  Google Scholar 

  28. D.G. Huang, S.J. Liao, W.B. Zhou, S.Q. Quan, L. Liu, Z.J. He, J.B. Wan, J. Phys. Chem. Solids 70, 853 (2009)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The Project was supported by Special and Key Laboratory of Functional Materials and Resource chemistry of Guizhou Provincial Education Department (GAFMRC201302), the joint funds of department of science & technology of Guizhou province, people’s government of Anshun city and Anshun university (LH[2014]7499), and National Natural Science foundation (Project No. 51302080) of China.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Qian Deng.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chen, XM., Liu, ZJ., Tang, JT. et al. La-modified mesoporous TiO2 nanoparticles with enhanced photocatalytic activity for elimination of VOCs. J Porous Mater 22, 361–367 (2015). https://doi.org/10.1007/s10934-014-9904-6

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-014-9904-6

Keywords

Navigation