Abstract
Two novel mesoporous cellular foams (MCFs) materials with well-defined large and aerogel-like mesostructure were successfully synthesized using tetraethyl orthosilicate as silica source, cyclohexane (CHE) as a swelling agent and triblock copolymer Pluronic P123 and F68 as a template, respectively. The effect of CHE on the expansion of the framework were characterized in detailed by small-angle X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption–desorption. The results showed that CHE was an effective swelling agent on the pore size of MCFs. All as-prepared materials were employed as the adsorbent to brominated flame retardants (BFRs) from environmental water samples. The adsorption study indicated the new materials exhibited superior adsorption capacity, the removal efficiencies of MCF-1-1.5 for seven BFRs reached 81.4–95.2 % in industrial wastewater. The recoveries of method were in the range of 86.3–105.7 % for Xiaoqing River sample and 74.6–114.6 % for chemical plant wastewater sample.
Similar content being viewed by others
References
C.A. de Wit, Chemosphere 46, 583 (2002)
M. Alaee, P. Arias, A. Sjodin, A. Bergman, Environ. Int. 29, 683 (2003)
R.J. Law, P. Bersuder, C.R. Allchin, J. Barry, Environ. Sci. Technol. 40, 2177 (2006)
Environmental Health Criteria 172, Tetrabromobisphenol A and Derivatives, International Programme on Chemical Safety, World Health Organization, Geneva (1995)
F.T. Dettmer, H. Wichmann, J. de Boer, M. Bahadir, Chemosphere 39, 1523 (1999)
A. Nakajima, D. Saigusa, N. Tetsu, T. Yamakuni, Y. Tomioka, T. Hishinuma, Toxicol. Lett. 189, 78 (2009)
A. Covaci, A.C. Gerecke, R.J. Law, S. Voorspoels, M. Kohler, N.V. Heeb, H. Leslie, C.R. Allchin, J. De Boer, Environ. Sci. Technol. 40, 3679 (2006)
G.B. Qu, A.F. Liu, T. Wang, C.L. Zhang, J.J. Fu, M. Yu, J.S. Sun, N.L. Zhu, Z.N. Li, G.H. Wei, Y.G. Du, J.B. Shi, S.J. Liu, G.B. Jiang, Environ. Sci. Technol. 47, 4760 (2013)
N.G. Dodder, A.M. Peck, J.R. Kucklick, L.C. Sander, J. Chromatogr. A 1135, 36 (2006)
K.W. George, M.M. Haggblom, Environ. Sci. Technol. 42, 5555 (2008)
Y. Tian, J. Chen, Y.Z. Ouyang, G.B. Qu, A.F. Liu, X.M. Wang, C.X. Liu, J.B. Shi, H.W. Chen, G.B. Jiang, Anal. Chim. Acta 814, 49 (2014)
G.B. Qu, J.B. Shi, T. Wang, J.J. Fu, Z.N. Li, P. Wang, T. Ruan, G.B. Jiang, Environ. Sci. Technol. 45, 5009 (2011)
R.J. Letcher, S.G. Chu, Environ. Sci. Technol. 44, 8615 (2010)
X.M. Wang, J.Y. Liu, Q. Liu, X.Z. Du, G.B. Jiang, Talanta 116, 906 (2013)
X.M. Wang, J.Y. Liu, A.F. Liu, Q. Liu, X.Z. Du, G.B. Jiang, Anal. Chim. Acta 753, 1 (2012)
H.H. Rao, X.M. Wang, X.Z. Du, Z.H. Xue, J. Porous Mater. 20, 1231 (2013)
C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, J.S. Beck, Nature 359, 710 (1992)
J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, J.L. Schlenker, J. Am. Chem. Soc. 114, 10834 (1992)
D.Y. Zhao, J.L. Feng, Q.S. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka, G.D. Stucky, Science 279, 548 (1998)
D.Y. Zhao, Q.S. Huo, J.L. Feng, B.F. Chmelka, G.D. Stucky, J. Am. Chem. Soc. 120, 6024 (1998)
P. Kipkemboi, A. Fogden, V. Alfredsson, K. Flodström, Langmuir 17(17), 5398 (2001)
J.M. Kim, Y. Sakamoto, Y.K. Hwang, Y.U. Kwon, O. Terasaki, S.E. Park, G.D. Stucky, J. Phys. Chem. B 106, 2552 (2002)
P. Schmidt-Winkel, W.W. Lukens Jr, P. Yang, D.I. Margolese, J.S. Lettow, J.Y. Ying, G.D. Stucky, Chem. Mater. 12, 686 (2000)
Q. Li, Z.X. Wu, D. Feng, B. Tu, D.Y. Zhao, J. Phys. Chem. C 114, 5012 (2010)
Acknowledgments
This work was generously supported by the Natural Science Foundation of China (Nos. 21467028, 21107086, 21265009, 21265018, 21265019, and 21327005), the Program for Chang jiang Scholars and Innovative Research Team, Ministry of Education, China (Grant No. IRT1283); the Program for Innovative Research Group of Gansu Province, China (Grant No.1210RJIA001), Key Laboratory of Polymer Materials of Gansu Province and the Key Laboratory of Ecological Environment Related Polymer Materials of Ministry of Education.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Wang, X., Lu, M., Pei, Y. et al. Two mesoporous cellular foams materials and their adsorption properties to brominated flame retardants. J Porous Mater 22, 83–90 (2015). https://doi.org/10.1007/s10934-014-9875-7
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10934-014-9875-7