Skip to main content
Log in

Mechanical Properties of Microcrystalline Cellulose (MCC) Filled Engineering Thermoplastic Composites

  • Original Paper
  • Published:
Journal of Polymers and the Environment Aims and scope Submit manuscript

Abstract

In this study, engineering thermoplastic composites were prepared from microcrystalline cellulose (MCC)-filled nylon 6. MCC were added to nylon 6 using melt mixing to produce compounded pellets. The MCC-filled nylon 6 composites with varying concentrations of MCC (from 2.5 to 30 wt%) were prepared by injection molding. The tensile and flexural properties of the nylon 6 composites were increased significantly with the addition of MCC. The maximum strength and modulus of elasticity for the nylon 6 composites were achieved at a MCC weight fraction of 20 %. The Izod impact strength of composites decreased with the incorporation of MCC without any surface treatments and coupling agent. This observation is quite expected for filled polymer systems and has been commonly observed. There was a strong correlation between density and tensile (r = 0.94) and flexural modulus of elasticity (r = 0.9). MCC filled composites manufactured by injection method had highly uniform density distribution through their thickness. The higher mechanical results with lower density demonstrate that MCC can be used as a sufficient reinforcing material for low cost, eco-friendly composites in the automotive industry especially for under-the-hood applications (engine covers, intake manifolds and radiator end tanks) as well as in other applications such as the building and construction industries, packaging, consumer products etc.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Field RJ (2003) Polymer science and technology, 2nd edn. Prentice Hall, Upper Saddle River, NJ

    Google Scholar 

  2. Fornes DT, Paul RD (2003) Crystallization behavior of nylon 6 nanocomposites. Polymer 44(14):3945–3961

    Article  CAS  Google Scholar 

  3. Jang PS, Kim D (2000) Thermal, mechanical, and diffusional properties of nylon 6/ABS polymer blends: compatibilizer effect. Polym Eng Sci 40(7):1635–1642

    Article  CAS  Google Scholar 

  4. Unal H, Findik F, Mimaroglu A (2003) Mechanical behavior of nylon composites containing talc and kaolin. J Appl Polym Sci 88(7):1694–1697

    Article  CAS  Google Scholar 

  5. Cho WJ, Paul RD (2001) Nylon 6 nanocomposites by melt compounding. Polymer 42(3):1083–1094

    Article  CAS  Google Scholar 

  6. Racz L, Pukánszky B Jr, Pozsgay A, Pukanszky B (2004) Polyamide 6/montmorillonite nanocomposites: effect of interaction on structure and properties. Prog Colloid Polym Sci 125:96–100

    CAS  Google Scholar 

  7. Avella M, Errico EM, Gentile G (2006) Nylon 6/calcium carbonate nanocomposites: characterization and properties. Macromol Sympos 234(1):170–175

    Article  CAS  Google Scholar 

  8. Xu X (2008) Cellulose fiber reinforced nylon 6 or nylon 66 composites. PhD Dissertation, Georgia Institute of Technology, Georgia

  9. Caulfield FD, Jacobson ER, Sears DK, Underwood HJ (2001) Woodpulp fibres as reinforcements for high-melting engineering thermoplastics for ‘under-the-hood’ automotive applications. In: The polymer processing. The Polymer Processing Society, Montreal, Canada, pp 1–10

  10. Jacobson R, Caulfield D, Sears K, Underwood J (2001) Low temperature processing (LTP) of ultra-pure cellulose fibers into nylon 6 and other thermoplastics. In: Sixth international conference on woodfiber/plastic composites. Forest Products Society, Madison, WI, pp 1–6

  11. Sears K, Jacobson R, Caulfield D, Underwood J (2001) Reinforcement of engineering thermoplastics with high-purity wood cellulose fibers. In: Sixth international conference on woodfiber–plastic composites. Forest Products Society, Madison, WI, pp 27–34

  12. Kiziltas A (2009) Microcrystalline cellulose-filled engineering thermoplastic composites. Master of Science Thesis, University of Maine, Orono, Maine, USA, pp 1–135

  13. Kiziltas A, Gardner DJ, Han Y, Yang H-S (2011) Dynamic mechanical behavior and thermal properties of microcrystalline cellulose (MCC)-filled nylon 6 composites. Thermochim Acta 519(1–2):38–43

    Article  CAS  Google Scholar 

  14. Kiziltas A, Nazari B, Gardner DJ, Bousfield DW (2014) Polyamide 6-cellulose composites: effect of cellulose composition on melt rheology and crystallization behaviour. Polym Eng Sci 54(4):739–746

    Article  CAS  Google Scholar 

  15. Snijder BHM, Wissing E, Modder FJ (1997) Polyolefins and engineering plastics reinforced with annual plant fibers. In: Seventh international conference on woodfiber–plastic composites. Forest Products Society, Madison, WI, pp 181–191

  16. Misra M, Mohanty AK, Tummala P, Drzal LT (2004) Injection molded biocomposites from natural fibers and modified polyamide. In: SPE Annual Technical Conference Proceedings, May 16–20, Chicago, IL

  17. Azizi Samir MA, Alloin F, Dufresne A (2005) Review of recent research into cellulosic whiskers, their properties and their application in nanocomposite field. Biomacromolecules 6(2):612–626

    Article  Google Scholar 

  18. Mathew AP, Oksman K, Sain M (2004) Mechanical properties of biodegradable composites from poly lactic acid (PLA) and microcrystalline cellulose (MCC). J Appl Polym Sci 97(5):2014–2025

    Article  Google Scholar 

  19. Petersson L, Oksman K (2006) Biopolymer based nanocomposites: comparing layered silicates and microcrystalline cellulose as nanoreinforcement. Compos Sci Technol 66(13):2187–2196

    Article  CAS  Google Scholar 

  20. Laka MG, Chernyavskaya SA (1996) Physicomechanical properties of composites containing thermocell microcrystalline cellulose as filler. Mech Compos Mater 32(4):381–386

    Article  Google Scholar 

  21. Maskavs M, Kalnins M, Reihmane S, Laka M, Chernyavskaya S (1999) Effect of water sorption of some mechanical parameters of composite systems based on low-density polyethylene and microcrystalline cellulose. Mech Compos Mater 35(1):55–62

    Article  CAS  Google Scholar 

  22. Maskavs A, Kalnins M, Laka M, Chernyavskaya S (2001) Physicomechanical properties of composites based on low-density polyethylene and cellulose-containing filers. Mech Compos Mater 37(2):159–166

    Article  CAS  Google Scholar 

  23. Panaitescu DM, Donescu D, Bercu C, Vuluga DM, Iorga M, Ghiurea M (2007) Polymer composites with cellulose microfibrils. Polym Eng Sci 47(8):1228–1234

    Article  CAS  Google Scholar 

  24. Panaitescu MD, Notingher VP, Ghiurea M, Ciuprina F, Paven H, Iorga M, Florea D (2007) Properties of composite materials from polyethylene and cellulose microfibrils. J Optoelectron Adv M9(8):2524–2528

    Google Scholar 

  25. JMP Statistical Discovery Software (2008) Version 8. SAS Institute, Inc., Cary, NC

  26. Jeong YG (2005) Fracture behaviour of wood plastic composite (WPC). PhD Thesis, Louisiana State University and Agricultural and Mechanical College, Louisiana

  27. QMS Density Profiler User’s Guide (2001) Model QDP-01X Quintek Measurement Systems, Inc., Knoxville, TN

  28. Ljunberg N, Cavaille J-Y, Heux L (2006) Nanocomposites of isotactic polypropylene reinforced with rod-like cellulose whiskers. Polymer 47(18):6285–6292

    Article  Google Scholar 

  29. Zaini MJ, Fuad MYA, Ismail Z, Mansor MS, Mustafah J (1996) The effect of filler content and size on the mechanical properties of polypropylene/oil palm wood flour composites. Polym Int 40(1):51–55

    Article  CAS  Google Scholar 

  30. Dikobe DG, Luyta AS (2007) Effect of filler content and size on the properties of ethylene vinyl acetate copolymer–wood fiber composites. J Appl Polym Sci 103(6):3645–3654

    Article  CAS  Google Scholar 

  31. Seydibeyoglu OM, Oksman K (2008) Novel nanocomposites based on polyurethane and micro fibrillated cellulose. Compos Sci Technol 68:908–914

    Article  Google Scholar 

  32. Kiziltas A, Erbas Kiziltas E, Boran S, Gardner DJ (2013) Micro- and nanocellulose composites for automotive applications. In: Proceedings of SPE automotive composites conference and exhibition (ACCE), September 11–13, Novi, MI

  33. Ozen E, Kiziltas A, Kiziltas EE, Gardner DJ (2013) Natural fiber blend-nylon 6 composites. Polym Compos 34(4):544–553

    Article  CAS  Google Scholar 

  34. Kiziltas A, Gardner DJ, Han Y, Yang H-S (2010) Determining the mechanical properties of microcrystalline cellulose (MCC)—filled PET/PTT blend composites. Wood Fiber Sci 42(2):165–176

    CAS  Google Scholar 

  35. Sanadi A, Caulfield D, Jacobson R (1997) Agro-fiber thermoplastic composites. In: Young RA, Rowell KJ, Rowell MR (eds) Paper and composites from agro-based resources, chapter 12. CRC Lewis Publishers, Boca Raton, FL, pp 377–402

  36. Bengtsson M, Oksman K (2006) The use of silane technology in crosslinking polyethylene/wood flour composites. Compos Part A Appl Sci Manuf 37(5):752–765

    Article  Google Scholar 

  37. Liang J-Z (2002) Tensile and impact properties of hollow glass bead-filled PVC composites. Macromol Mater Eng 287(9):588–591

    Article  CAS  Google Scholar 

  38. Cui HY, Tao J, Noruziaan B, Cheung M, Lee S (2010) DSC analysis and mechanical properties of wood–plastic composites. J Reinf Plast Compos 29(2):278–289

    Article  CAS  Google Scholar 

  39. Klyosov AA (2007) Wood–plastic composites. Wiley, New Jersey

    Book  Google Scholar 

  40. Cualfiled FD, Jacabson ER, Sears DK, Underwood HJ (2001) Fiber reinforced engineering plastics. In: Proceedings of the 2nd international conference on advanced engineered wood composites. University of Maine, Maine, pp 1–6

Download references

Acknowledgments

The republic of Turkey, Ministry of National Education has been greatly acknowledged for the scholarship of the researcher Alper Kiziltas to do this study at the University of Maine. The authors thank Chris West for the sample preparation. The authors would also like to thank Maine Agricultural and Forest Experiment Station (MAFES) project ME09615-08MS and the Wood Utilization Research Hatch 2007–2008 project. This is fourth paper of the Maine Agricultural and Forest Experiment Station.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Alper Kiziltas.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kiziltas, A., Gardner, D.J., Han, Y. et al. Mechanical Properties of Microcrystalline Cellulose (MCC) Filled Engineering Thermoplastic Composites. J Polym Environ 22, 365–372 (2014). https://doi.org/10.1007/s10924-014-0676-5

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10924-014-0676-5

Keywords

Navigation